Cation exchange reaction is a strong tool for the synthesis of new ionic nanomaterials. Most of them are isolated nanoparticles with simple geometric features, such as nanodots, nanorods and nanospheres. In this work, we demonstrated that ordered mesoporous CdS with a complex cubic Ia3d gyroidal 3D bicontinuous porous structure and large particle size can be successfully converted to crystallin...

Cation exchange is a powerful tool for the synthesis of nanostructures such as core-shell nanocrystals, however, the underlying mechanism is poorly understood. Interactions of cations with ligands and solvent molecules are systematically ignored in simulations. Here, we introduce the concept of pseudoligands to incorporate cation-ligand-solvent interactions in molecular dynamics. This leads to ...

Magnetic metal (Mn, Fe, Co, and Ni) oxides nanocrystals with small size and uniform size distribution are synthesized via a cation-exchange reaction. Two experimental stages are included in the synthesis of metal oxides nanocrystals. Firstly, Cu(OH)2 decomposes to CuO nanocrystals, induced by free metal cations. Compared to CuO nanocrystals produced without any free metal cation, the free metal...

For three types of colloidal magnetic nanocrystals, we demonstrate that postsynthetic cation exchange enables tuning of the nanocrystal's magnetic properties and achieving characteristics not obtainable by conventional synthetic routes. While the cation exchange procedure, performed in solution phase approach, was restricted so far to chalcogenide based semiconductor nanocrystals, here ferrite-...

The anthocyanins of Siahe Sardasht variety (Vitis vinifera L. var. S.S.) were extracted from freezed samples and were purified by adsorption on cation-exchange resin column. Individual pigments were separated by TLC on cellulose plates. Monomeric anthocyanin content that was determined by pH-differential, was 1740.11±3.58 mgL?1 (based on malvidin 3-glucose). Five major pigments were identified ...

Potential applications of nickel nanoparticles demand the synthesis of self-protected nickel nanoparticles by different synthesis techniques. A novel and simple technique for the synthesis of self-protected nickel nanoparticles is realized by the inter-matrix synthesis of nickel nanoparticles by cation exchange reduction in two types of resins. Two different polymer templates namely strongly ac...

the anthocyanins of siahe sardasht variety (vitis vinifera l. var. s.s.) were extracted from freezed samples and were purified by adsorption on cation-exchange resin column. individual pigments were separated by tlc on cellulose plates. monomeric anthocyanin content that was determined by ph-differential, was 1740.11±3.58 mgl?1 (based on malvidin 3-glucose). five major pigments were identified ...

Because the boiler is developed to the trend of large size, high temperature and high pressure, so the requirement of water quality for the boiler makeup water is higher and higher, and that needs to almost get rid of all salts in the water. So anion-cation exchange technology has been developed quickly. For example, use the H cation exchanger to exchange various cations in the water and give o...

Solid-phase extraction (SPE) procedures were developed for rapid cleanup and determination of thiabendazole and carbendazim in orange, apple, and grape juices. Samples were prepared by using an SPE cartridge containing a mixed-mode sorbent with both reversed-phase and strong cation-exchange chemistries. Analysis was by liquid chromatography with photodiode-array UV detection. Orange juice was a...