introduction: dye removal from industrial wastewater has been considered as one of the most environmental issues. recently, new methods of treatment such as catalytic ozonation have been used to increase dye removal efficiency. so, the efficiency of catalytic ozonation by copper coated zeolite as a catalyst in the removal of reactive red 198 was investigated. materials & methods: in order to re...

Two types of stainless steel microstructured reactors for catalytic gas-phase reactions have been developed and characterized with respect to heir thermal behaviour under non-stationary temperature conditions. One of the reactors used (FTC-I) allowed periodic temperature changes up to 00 K with a frequency of 0.05 Hz. However, a broad temperature gradient of 80 K developed inside the reactor. A...

background: sulfur compounds must be removed from petroleum because they contribute to environmental pollution. a strong alkaline solution such as caustic soda is used to remove these compounds. this spent caustic has high values for chemical oxygen demand (cod) concentration, ph and total sulfur. in this study, the regeneration and treatment methodology of sulfidic spent caustic was investigat...

Benzene alkylation with propylene was studied in the gas phase using a catalytic membrane reactor and a fixed-bed reactor in the temperature range of 200-300 °C and with a weight hourly space velocity (WHSV) of 51 h-1. β-zeolite was prepared by hydrothermal synthesis using silica, aluminum metal and TEAOH as precursors. The membrane's XRD patterns showed good crystallinity for the β-zeolite fil...

A dehydrogenation anode is reported for hydrocarbon proton conducting solid oxide fuel cells (SOFCs). A Cu-Cr(2)O(3) nanocomposite is obtained from CuCrO(2) nanoparticles as an inexpensive, efficient, carbon deposition and sintering tolerant anode catalyst. A SOFC reactor is fabricated using a Cu-Cr(2)O(3) composite as a dehydrogenation anode and a doped barium cerate as a proton conducting ele...

Abstract Gas to liquid (GTL) process involves heterogeneous catalytic chemical reactions that convert synthesis gas to hydrocarbons and water vapor. A three phase reactor, called Low temperature Fischer-Tropsch (LTFT) is commonly applied for GTL process. In this reactor the gaseous phase includes the synthesis gas, light hydrocarbons and water vapor, the liquid phase is a mixture of the h...

An Atomic Force Microscope (AFM) has been integrated in a miniature high-pressure flow reactor for in-situ observations of heterogeneous catalytic reactions under conditions similar to those of industrial processes. The AFM can image model catalysts such as those consisting of metal nanoparticles on flat oxide supports in a gas atmosphere up to 6 bar and at a temperature up to 600 K, while the ...

The kinetics of the esterification of n-butanol with acetic acid have been studied in a batch and in a tubular reactor. The best model for obtaining the esterification rate with a partially wet ion exchanger (270/o water contents) is obtained by assuming a pseudohomogeneous system, while the kinetics of dry ion exchangers is best represented by a model derived from assumptions based on a hetero...

To accelerate the commercial application of mixed-conducting membrane reactor for catalytic reaction processes, a robust mixed-conducting multichannel hollow fiber (MCMHF) membrane reactor was constructed and characterized in this work. The MCMHF membrane based on reduction-tolerant and CO2-stable SrFe0.8Nb0.2O3-δ (SFN) oxide not only possesses a good mechanical strength, but also has a high ox...

Steady-state multiplicity in individual catalyst particles can be exploited to produce concentration patterns in a catalytic reactor. Thus, stable, steady-state, spatial patterns can be created in a packed bed reactor by providing for an initial pattern using multiple feeds at different points along the length of the reactor as a start-up strategy. It is shown that the formation of such pattern...