The lean body weight phenotype of hepatic lipase (HL)-deficient mice (hl(-/-)) suggests that HL is required for normal weight gain, but the underlying mechanisms are unknown. HL plays a unique role in lipoprotein metabolism performing bridging as well as catalytic functions, either of which could participate in energy homeostasis. To determine if both the catalytic and bridging functions or the...

A series of palladium-based catalysts of metal alloying (Sn, Pb) and/or (N-doped) graphene support with regular enhanced electrocatalytic activity were investigated. The peak current density (118.05 mA cm(-2)) of PdSn/NG is higher than the sum current density (45.63 + 47.59 mA cm(-2)) of Pd/NG and PdSn/G. It reveals a synergistic electrocatalytic oxidation effect in PdSn/N-doped graphene Nanoco...

Copper (I) oxide microparticles with the morphology of cubic and hollow sphere were synthesized with the assistance of surfactant as the shape controller. Both particles were then subjected to study the catalytic activity and observed the results of shape effects of catalysts on rate of catalytic reaction. The decolorizing reaction of crystal violet and sodium hydroxide was chosen and measured ...

A series of copper and cobalt substituted nanospinel ferrites have been synthesized by the hydrothermal method. These compounds were characterized by FT-IR, XRD, EDX, SEM and VSM techniques. All of the synthesized nanospinel ferrites were found to be highly efficient and magnetically recoverable in the solvent-free synthesis of substituted 2,6-(2-hydroxybenzyl)-phenols (trisphenols). A wide ran...

Stereoelectronic effects is a bridge between structure and reactivity [1]. Anomeric effect plays an important role in the domain of stereoelectronic interaction and can be used for description of several unusual phenomena. Intramolecular negative hyperconjugation is also known as anomeric effect [2]. In anomeric effect, both donor (lone pairs) and acceptor groups (electronegative elements) coex...

Catalytic promiscuity can facilitate evolution of enzyme functions-a multifunctional catalyst may act as a springboard for efficient functional adaptation. We test the effect of single mutations on multiple activities in two groups of promiscuous AP superfamily members to probe this hypothesis. We quantify the effect of site-saturating mutagenesis of an analogous, nucleophile-flanking residue i...

Enzymes use protein architecture to impose specific electrostatic fields onto their bound substrates, but the magnitude and catalytic effect of these electric fields have proven difficult to quantify with standard experimental approaches. Using vibrational Stark effect spectroscopy, we found that the active site of the enzyme ketosteroid isomerase (KSI) exerts an extremely large electric field ...

a new simple arid rapid catalytic kinetic method for determination of trace amounts of chromium (110 isdescribed. the method is based on the catalytic effect of chromium (iii) on the reduction of methylene blue byascorbic acid in acidic media. the reaction monitored smectrophotomenically by measuring the decrease ofabsorbance at 664 nm at 25 c. the fixed-time method was used for the first 300 s...

the mixed metal nanocomposite mgo∙al2o3∙zno has been prepared by coprecipitation method. the product was characterized by xrd. the average particle size was found to be 34.89 nm from xrd data. sem and sem-eds were studied for evaluating surface morphology and elemental composition. the ftir spectrum of prepared mixed metal nanocomposites mgo∙al2o3∙zno and mgo∙al2o3∙zno-curcumin were studied. th...

background: catalytic ozonation has recently been applied as a new method of contaminant removal from water and wastewater. in this study, copper coated pumice and zeolite were used to catalyze the ozonation of phenol as a target pollutant from aqueous solutions. methods: the pumice and zeolite stone were modified by cuso 4 (1n). modified pumice and zeolite were characterized by adsorption/deso...