In this study, we present the first experimental results for stable barium (Ba) isotope ((137)Ba/(134)Ba) fractionation during low-temperature formation of the anhydrous double carbonate BaMn[CO(3)](2). This investigation is part of an ongoing work on Ba fractionation in the natural barium cycle. Precipitation at a temperature of 21±1°C leads to an enrichment of the lighter Ba isotope described...

A ureolytic biodeposition treatment was applied to five types of limestone in order to investigate the effect of pore structure on the protective performance of a biogenic carbonate surface treatment. Protective performance was assessed by means of transport and degradation processes, and the penetration depth of the treatment was visualized by microtomography. Pore size governs bacterial adsor...

The Chehel Kaman Formation of the upper Paleocene age formed from carbonate and siliciclastic sediments is located, in the Kapeh Dagh Sedimentary Basin. Two sections where considered for the purpose of research into the effective diagenetic processes of this formation. The Cheshmeh Qorban section with a thickness of 270.8m located 140km down the Mashhad – Sarakhs Highway while the Shourlog Sect...

Employing the widely used ammonium carbonate diffusion method, we demonstrate that altering an extrinsic parameter—desiccator size—which is rarely detailed in publications, can alter the route of crystallization. Hexagonally packed assemblies of spherical magnesium-calcium carbonate particles or spherulitic aragonitic particles can be selectively prepared from the same initial reaction solution...

Experimental results supported by density functional theory calculations show carbonate formation and reaction on atomic oxygen precovered Au(111). Oxygen mixing is observed in temperature-programmed desorption measurements when a Au(111) precovered with 16O is exposed to isotopically labeled CO2 (C18O2). The presence of 16O18O is attributed to surface carbonate formation and decomposition at s...

Early-stage reaction mechanisms for aragonite-promoting systems are relatively unknown compared to the more thermodynamically stable calcium carbonate polymorph, calcite. Using cryoTEM and SEM, the early reaction stages taking place during aragonite formation were identified in a highly supersaturated solution using an alcohol-water solvent, and an overall particle attachment growth mechanism w...

Nickel compounds are recognized to cause nasal and lung cancers. Magnesium is an effective protector against nickel-induced carcinogenesis in vivo, although its mechanisms of protection remain elusive. The effects of magnesium carbonate on the cytotoxicity and genotoxicity induced by nickel subsulfide were examined with respect to the inhibition of cell proliferation, micronuclei formation, DNA...

the upper cretaceous carbonate sequence of ab-deraz formation is well exposed in the kopet- dagh basin. this formation comprises marly limestone and three chalky limestone units. chalky limestone of ab-deraz formation is mainly composed of calcareous dinoflagellate (pithonellid calcispher), cocolithofore and planktonic foraminifera. carbon and oxygen stable isotopes analysis of the third chalky...

Objective: The Asmari Formation is characterised by alternation thick carbonate and marl sequence of the Oligocene- Miocene in the Zagros Basin, southwest of Iran that were deposited on the shelf of Eastern Paratethys. Methods: This formation is exposed at Tang-e-Khoshk in the Fars subcoastal zone with a thickness of 286 m comprising alternation of medium and thick to massive bedded carbonates,...