Benzene and methanol make a minimum boiling point homogeneous binary azeotrope with the mole ratio 2:3. Some characteristic vibrational modes, as well as (1)H NMR signals change due to the azeotrope formation. The extend of interaction of these molecules causes significant changes on some vibrational modes involved, and (1)H NMR signals show some changes on their position. No IR, Raman, and NMR...

Pool boiling experiments were conducted with three horizontal, flat, silicon surfaces, two of which were coated with vertically aligned multiwalled carbon nanotubes (MWCNTs). The two wafers were coated with MWCNT of two different thicknesses: 9 m (Type-A) and 25 m (Type-B). Experiments were conducted for the nucleate boiling and film boiling regimes for saturated and subcooled conditions with l...

By means of the new software MOLGEN-QSPR, a multilinear regression model for the boiling points of lower fluoroalkanes is established. The model is based exclusively on simple descriptors derived directly from molecular structure and nevertheless describes a broader set of data more precisely than previous attempts that used either more demanding (quantum chemical) descriptors or more demanding...

The neutronics performance of the EVOLVE concept was analyzed using two-dimensional calculations. The vapor fraction in the boiling blanket has a small impact on the nuclear performance parameters. For the worst case condition with the highest predicted vapor fraction distribution, all nuclear performance parameters are acceptable with a comfortable margin. The EVOLVE boiling blanket is expecte...

We study heat transfer from a heated nanoparticle into surrounding fluid using molecular dynamics simulations. We show that the fluid next to the nanoparticle can be heated well above its boiling point without a phase change. Under increasing nanoparticle temperature, the heat flux saturates, which is in sharp contrast with the case of flat interfaces, where a critical heat flux is observed fol...

Chromatography is an analytical technique employed for purification and separation of organic and inorganic substances including characterisation and quantitative measurement of compounds (table). Basically there are two types: l. Gas chromatography (GC), 2. Liquid chromatography (LC). Although discovered in 1906 by Tshett, developed in the 1950s as the GC technique where the mobile phase are g...