Chemical redox reactions have been exploited to transform unreactive vinylferrocene into a powerful dienophile for the Diels-Alder reaction and reactive substrate for thiol addition reactions upon conversion to its ferrocenium state. We have further investigated the ability of these reactions to facilitate redox-auxiliary-like reactivity by further hydrogenolyisis of the Diels-Alder adduct to t...

[reaction: see text] Two different routes to the tricyclic core of Garcinia-derived natural products are described. The first approach is based on a tandem Claisen/Diels-Alder rearrangement and delivers the desired lactone 14. The second approach, employing a Wessely oxidation/Diels-Alder protocol, leads to the same caged heterocycle, albeit with modified constitution.

On the basis of the Diels-Alder reaction of graphite and tetracyanoethylene, graphite has been mechanically exfoliated into graphene adducts in a yield up to 38%. The graphene adduct can restore its conjugated structure via retro-Diels-Alder reaction under mild conditions, exhibiting a high conductivity of 1035 S m(-1).

SpnF is the first monofunctional Diels-Alder/[6+4]-ase that catalyzes a reaction leading to both Diels-Alder and [6+4] adducts through a single transition state. The environment-perturbed transition-state sampling method has been developed to calculate free energies, kinetic isotope effects, and quasi-classical reaction trajectories of enzyme-catalyzed reactions and the uncatalyzed reaction in ...

One hundred years after the birth of Kurt Alder and seventy-five years after the discovery of his famous reaction, one of the most important and fascinating transformations in chemistry, research on that process continues to surprise, excite, delight, and inform the chemical community. This article is based on presentations given first at the University of Cologne, Germany (Kurt Alder lecture, ...

The enzyme SpnF, involved in the biosynthesis of spinosyn A, catalyzes a formal [4+2] cycloaddition of a 22-membered macrolactone, which may proceed as a concerted [4+2] Diels-Alder reaction or a stepwise [6+4] cycloaddition followed by a Cope rearrangement. Quantum mechanics/molecular mechanics (QM/MM) calculations combined with free energy simulations show that the Diels-Alder pathway is favo...

Species information is a key component of any forest inventory. However, when performing forest inventory from aerial scanning Lidar data, species classification can be very difficult. We investigated changes in classification accuracy while identifying five individual tree species (Douglas-fir, western redcedar, bigleaf maple, red alder, and black cottonwood) in the Pacific Northwest United St...

Riparian wetlands are dynamic components of landscapes. Located between uplands and aquatic environments, riparian habitats intercept sediments and nutrients before they enter aquatic environments. They are a source of organic matter and nutrients to aquatic systems, and they provide important habitat for animals, often serving as corridors for the movement of animals between habitats in fragme...

This study was aimed to determine combustion characteristics and decay resistance of Spruce [Picea orientalis (L.)], Fir (Abies nordmanniana), Alder [Alnus glutinosa (L.)], and Iroko (Milicia excelsa) woods impregnated with ammonium tetrafluoro borate (1 to 3%) and the mixture of cement and borax (6% to 9%). The combustion test method was performed in three stages: flame stage, without flame st...