The effect of substituents in the aniline donor and type heterocyclic acceptor/donor moieties on yields 1,2-trans- 1,1-isomer ethylene D-π-A chromophores Pd-catalyzed Heck reaction has been studied. Various – derivatives quinoline, quinoxaline, benzothiazole, carbazole indolizine were synthesized.

Stable organoboron complexes as classic fluorescent molecules have found various applications in biotechnology and material sciences. A new class of isoindolin-1-one based BF2 complexes containing pyridine or benzothiazole groups has been prepared from a facile "one-pot" reaction and characterized structurally, spectroscopically and electrochemically. These novel dyes show broad and intense abs...

Benzothiazole derivatives are widely used as industrial chemicals; mainly as fungicides in the leather and wood processing industries, herbicides, components in automobile antifreeze, corrosion inhibitor in cooling systems, and in particular as vulcanization accelerators in the rubber industry1. Benzothiazole enters the environment from a variety of sources such as the leaching of rubber produc...

A series of 6-amidinobenzothiazoles, linked via phenoxymethylene or directly to the 1,2,3-triazole ring with a p-substituted phenyl benzyl moiety, were synthesised and evaluated in vitro against four human tumour cell lines protozoan parasite Trypanosoma brucei. The influence type amidino substituent linker on antiproliferative antitrypanosomal activities was observed, showing that imidazoline ...

A highly selective fluorescent probe for a protein tyrosine phosphatase (PTP) was designed by a simple phosphorylation of the 2-(2'-hydroxyphenyl)benzothiazole (HBT) chromophore: upon selective enzymatic hydrolysis, an excited-state intramolecular proton transfer (ESIPT) occurs, resulting in a large Stokes shift.

The one-pot three-component reaction of 2-aminobenzothiazole, benzaldehyde derivatives and β-ketoester, β-diketone or malonate derivatives in solvent-free conditions provides the corresponding pyrimido[2,1-b]benzothiazole derivatives at 60 ̊C in 60% 72% yields without using any catalyst in an optimistic time.

Electrostatic interactions between an ESIPT molecule 2-(5'-amino-2'-hydroxyphenyl)benzothiazole (AHBT) and a phenylborate derivative give blue-green emission in acetic acid solution, but interestingly, vigorous (or mechanical) shaking of the solution leads to the formation of organic AHBT nanoparticles, which results in fluorescence colour switching from blue-green to yellow-orange.

The reactions of tetrachloroauric(III) acid (HAuCl4) with the thioamides; 2-mercapto-benzothiazole (mbztH) and 5-ethoxy-2-mercapto-benzimidazole (EtmbzimH) lead to the desulfuration of the ligands and the formation of the ionic complexes {[AuCl4]- [bztH2]+} (1), and {[AuCl4]- [EtbzimH2]+ (H2O)} (2) (where bztH2+ and EtbzimH2+ are the desulfurated cations of the starting ligands). The reaction o...