The paper presents the use of a Mass Separation Agent (entrainer) in reactive distillation processes. This can help to overcome limitations due to distillation boundaries, and in the same time increase the degrees of freedom in design. The catalytic esterification of fatty acids with light alcohols C2-C4 is studied as application example. Because the alcohol and water distillate in top simultan...

Bioethanol is among the most promising of biofuels because it has an energy content similar to gasoline while generating lower pollutant emissions than gasoline. But, in order to be used as an automotive fuel mixed with gasoline, ethanol must have less than 0.5 wt % of water. To achieve required ethanol purity, in light of the fact that the ethanol water mixture forms an azeotrope, unconvention...

Feasibility of batch extractive distillation in rectifying column with a middle boiling entrainer is theoretically and experimentally studied. These processes are preferable when the entrainer is already present in the mixture to be separated. Separation of methyl acetate and cyclohexane (forming minimum boiling azeotrope) using carbon tetrachloride, and separation of chloroform and ethyl aceta...

THE EFFECT OF METHOXYFLURANE on the sensitivity of the heart to epinephrineinduced ventricular arrhythmias has not been clearly defined. On the one hand, animal experiments have been reported which found that methoxyflurane increases ventricular arrhythmias associated with epinephrine administration. 1,~ On the other hand, other studies have found that methoxyflurane protects against arrhythmia...

A novel approach for enclosing all homogeneous azeotropes in multicomponent mixtures is presented. The thermodynamic criteria for azeotropy are outlined, and mathematical equations for each criterion are developed. The global optimization approach is based on developing convex underestimators which are coupled with a branch and bound framework in which upper and lower bounds on the solution are...

The biomass i.e. wheat-hemlock used in this study was first characterized for its composition. The physical and chemical characterization of biomass was estimated using proximate analysis, calorific value, crystallinity, devolatilization behaviour, ultimate analysis, ICP-MS of ash, FT-IR, XRD, CHNS, and HPLC analysis. For commercial purpose the same biomass was used for conversion to bio-oil by...

Translation of new 18F-fluorination reactions to produce radiotracers for human positron emission tomography (PET) imaging is rare because the chemistry must have useful scope and the process for 18F-labeled tracer production must be robust and simple to execute. The application of transition metal mediators has enabled impactful 18F-fluorination methods, but to date none of these reactions hav...

Styrene-butadiene (SBR) and acrylonitrile-butadiene (NBR) rubber blends with tetramethyl thiuram disulfide (TMTD) monosulfide (TMTS) accelerators environmentally friendly plasticizers, obtained from PET recycling biobased resources (LA/PG/PET/EG/LA), were prepared. The mechanical properties of the products tested compared those commercial dioctyl terephthalate (DOTP). TMTS was prepared by simpl...