Wire + Arc Additive Manufacture is an Manufacturing process that requires a substrate to initiate the deposition process. In order reduce material waste, build and lead time, improve efficiency, it desirable include this in final part design. This approach valid option only if interface between deposited metal properties conform design specifications. The effect of type on microstructure alumin...

The morphological evolution during spinodal decomposition of a binary alloy thin film elastically constrained by a substrate is studied. Elastic solutions, derived for elastically anisotropic thin films subject to the mixed stress-free and constraint boundary conditions, are employed in a three-dimensional phase-field model. The Cahn–Hilliard diffusion equation for a thin film boundary conditio...

A High Power Impulse Magnetron Sputtering (HiPIMS) method for depositing TiAlN environmental barrier coatings on the surface of Ti-48Al-2Cr-2Nb alloy was developed in view of their exploitation in turbine engines. Three differently engineered TiAlN films were processed and their performance compared. Bare intermetallic alloy coupons and coated specimens were submitted to thermal cycling under o...

This paper describes the design, manufacturing and characterization of newly developed mixed thick-/thin film thermoelectric microgenerators based on magnetron sputtered constantan (copper-nickel alloy) and screen-printed silver layers. The thermoelectric microgenerator consists of sixteen thermocouples made on a 34.2 × 27.5 × 0.25 mm³ alumina substrate. One of thermocouple arms was made of mag...

co-fe films were electrodeposited on cu substrate from electrolytes with different co concentration  levels. x-ray diffraction (xrd) was used  to  investigate  the  films  crystal  structures. the  results  indicate that  if  the  co  concentration  is  less  that  the  fe  concentration,  the cubic  structure  appears  in  the  films, while  the  hexagonal  structure dominates when  the co  co...

We have performed a high-resolution synchrotron radiation photoelectron spectroscopy study of the initial growth stages of the ZnPd near-surface alloy on Pd(111), complemented by scanning tunnelling microscopy data. We show that the chemical environment for surfaces containing less than half of one monolayer of Zn is chemically distinct from subsequent layers. Surfaces where the deposition is p...

The effect of superposed transitions in actuators with layered shape memory alloy (SMA) films undergoing martensitic phase transformation is analyzed in terms of a model developed for two layers of different composition, deposited at the same temperature on a substrate. A significant difference is observed in the actuation versus temperature relationship, depending on the thermal and elastic pr...

We have performed a high-resolution synchrotron radiation photoelectron spectroscopy study of the initial growth stages of the ZnPd near-surface alloy on Pd(111), complemented by scanning tunnelling microscopy data. We show that the chemical environment for surfaces containing less than half of one monolayer of Zn is chemically distinct from subsequent layers. Surfaces where the deposition is p...

The indentation of a brittle film on a ductile substrate is analysed for obtaining the interface toughness. This measurement method of adhesion provides a simple technique for sampling a small area of the interface on practical geometries with common laboratory equipment. Mechanics solutions are presented to access the interface toughness, Fc, from measurements of the applied load, delamination...

Nanoporous materials represent a unique class of materials, given to their unforeseen magnetic, mechanical, optical and catalytic properties arising from network pores ligaments. Here polycrystalline thin film FePd is considered as starting system, in which the porosity induced via dealloying. This process determines removal iron alloy diffusion palladium on surface, turn influences evolution m...