نتایج جستجو برای: 3 c pyrazoles

تعداد نتایج: 2600367  

Journal: :Chemistry 2016
Etienne Schmitt Armen Panossian Jean-Pierre Vors Christian Funke Norbert Lui Sergiy Pazenok Frédéric R Leroux

A novel approach towards highly functionalized fluoroalkyl pyrazoles was developed by using fluoroalkyl amino reagents in combination with a variety of fluorinated ketimines. Tuneable introduction of fluoroalkyl groups in the 3- and 5-positions was possible by using vinamidinium intermediates or the corresponding enamino ketones after hydrolysis. These high-value building blocks can give rise t...

2012
Viktor A Zapol’skii Jan C Namyslo Armin de Meijere Dieter E Kaufmann

The nitropolychlorobutadienes 3, 4 are valuable building blocks for various amination and successive heterocyclization products. Nucleophilic substitution reactions of the partially protected, bioactive amines 1, 2 with either vinyl, imidoyl or carbonyl chlorides result in the formation of the enamines 11, 12, 13, 16, 25, the amidine 6, and the amides 20, 21, respectively. In the following, cyc...

Journal: :Chemical communications 2012
Amila A Dissanayake Aaron L Odom

A simple titanium complex catalyzes the coupling of alkynes, isonitriles, and monosubstituted hydrazines to generate substituted pyrazoles in a single step.

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