Six metal-organic frameworks, namely, [Cd(μ(2)-HDMPhIDC)(Py)](n) (H(3)DMPhIDC = 2-(3,4-dimethylphenyl)-1H-imidazole-4,5-dicarboxylic acid, Py = pyridine) (1), [Sr(μ(2)-HDMPhIDC)(H(2)O)](n) (2), {[M1(3)(μ(3)-DMPhIDC)(2)(H(2)O)(6)]·2H(2)O}(n) (M1 = Zn (3), or Mn (4)), [M2(μ(2)-HDMPhIDC)(H(2)O)(2)](n) (M2 = Mg (5), or Ca (6)), have been hydro(solvo)thermally synthesized and structurally characteri...

The desolvation of lattice methanol from between the 1D chains in {[Cu(4,4'-bipyridine)(ccnm)(2)].4MeOH} (ccnm = carbamoylcyanonitrosomethanide) under ambient conditions, a weight loss of 22.4%, results in a solid state conversion to the 3D network [Cu(4,4'-bipyridine)(ccnm)(2)].

The coordination polymer [Zn(2)(1,2-bda)(2)(bpe)]·MeOH, which exhibits solvochromic effects upon reversible linear alcohol removal and adsorption, can be turned into [Zn(2)(1,2-bda)(2)(tpcb)(0.5)] in two-step SCSC transformations.

We present a molecular dynamics study on the stretching of a linear polymer chain that is adsorbed at the junction of two intersecting flat surfaces of varying alignments. We observe a transition from a two-dimensional to one-dimensional (1D) structure of the adsorbed polymer when the alignment, i.e., the angle between the two surfaces that form a groove, θ, is below 135°. We show that the radi...

The 1D coordination polymer, [Cu2(μ2OH)2(DABA)2]n (1), (HDABA = 4-Diallylamino-benzoic acid) is characterized by Single crystal X-Ray diffraction analysis. structure switches to a 2D geometry hydrogen bonding interactions. Hand grinding aqueous suspension of the 1, present in nano regime av. 100 nm dimension and shows catalytic performance reduction toxic nitrophenols corresponding aminophenols...

The use of simple plasma treatments and polymer deposition to tailor the anisotropic wetting properties of one-dimensional (1D) submicrometer-scale grooved surfaces, fabricated using interferometric lithography in photoresist polymer films, is reported. Strongly anisotropic wetting phenomena are observed for as-prepared 1D grooved surfaces for both positive and negative photoresists. Low-pressu...

in this study, we synthesis one-dimensional (1d) manganese(iii) schiff base coordination polymer [mn(brsalophen)(μ1,3-n3)]n by reaction of mncl2·6h2o and tetradentate schiff base ligand brsalophen at the presence of nan3 in methanol and characterized by elemental analyses (chn) and ft-ir spectroscopy. it was used as a new precursor to prepare spinel type manganese oxide nanowires by a facile so...

Compound [Cu(3)(N(3))(6)(DMF)(2)](n) () was initially obtained in a serendipitous way during efforts to prepare a Cu(II)/N(3)(-)/Mebta coordination polymer (Mebta = 1-methylbenzotriazole). With the identity of established by single-crystal crystallography, a rational preparative route to this complex was designed and carried out by reacting Cu(ClO(4)).6H(2)O with two equivalents of NaN(3) in DM...