The voltammetric characteristics of bismuth(III)-oxinate in chloroform at the mercury electrode were investigated and a quasi-reversible behavior for Bi(III) oxinate reduction was confirmed. Preceded by the extraction of Bi(III) oxinate in chloroform, differential pulse polarography was developed in the extracts for determination of the trace-bismuth. The linear range of the calibration gra...

A new Al(III) selective membrane based on 5-bromo(salicylidene-2-amino thiophenol) as a neutral carrier in a poly(vinyl chloride) (PVC) matrix is coated on platinum wire to determine trace amounts of Al(III) ion in various samples. The sensor exhibits a good response for Al(III) ion over a wide concentration range of 5.20 × 10-7 to 1.00 × 10-2 M  with Nernstian slope of 19...

lanthanide(iii) chloro complexes of 4[n-(4’-hydroxy-3’-methoxybenzalidene) amino] antipyrine semicarbazone (hmbaaps) (i) and 4[n-(3’,4’,5’-trimethoxybenzalidene) amino] antipyrine semicarbazone (tmbaaps) (ii) with the general composition lncl3.2l (ln = la, pr, nd, sm, gd, tb, dy or ho; l = hmbaaps or tmbaaps) are reported. all the complexes were synthesized in ethanolic medium and refluxed the ...

a poly(vinyl chloride) membrane based on a new a-dioxime derivative as membrane carrier was prepared andinvestigated as a cr(iii) selective electrode. the electrode exhibits a good potentiometric response for cr(iii)over a wide concentration range 1.0 x 10-6 to 1.0 x 10-1 m with a slope 19.5+0.5 mv/decade and low detectionlimit of 8.9 x 10-7 m. it has a fast response time < 15 s. the best perfo...