Polycrystalline Er-Sc silicates (Er x Sc2-x Si2O7 and Er x Sc2-x SiO5) were fabricated using multilayer nanostructured films of Er2O3/SiO2/Sc2O3 deposited on SiO2/Si substrates by RF sputtering and thermal annealing at high temperature. The films were characterized by synchrotron radiation grazing incidence X-ray diffraction, cross-sectional transmission electron microscopy, energy-dispersive X...

The structure of haiweeite, Ca[(UO2)2Si5O12(OH)2](H2O)3, Z = 4, orthorhombic, a 7.125(1), b 17.937(2), c 18.342(2) Å, V 2344.3(7) Å3, space group Cmcm, has been solved by direct methods and refined by full-matrix least-squares techniques to an agreement index (R1) of 4.2% for 1181 unique observed reflections (|Fo| ≤ 4 F) collected using MoK X-radiation and a CCDbased area detector. The structur...

Using a radiative transfer code we have studied the dust shells of the two OH/IR stars IRAS 17004-4119 (OH344.93) and IRAS 17411-3154 (OH357). The ISO-SWS spectra of both sources exhibit deep amorphous silicate absorption bands at 9.8 and 17.5 μm together with crystalline silicate emission bands at 33.6, 40.5 and 43 μm. In both sources the 9.8 μm silicate band shows a shoulder at 11.2 μm. The a...

Interactions of fluoride anions and organocations with crystalline silicate frameworks are shown to depend subtly on the architectures of the organic species, which significantly influence the crystalline structures that result. One- and two-dimensional (2D) (1)H, (19)F, and (29)Si nuclear magnetic resonance (NMR) spectroscopy measurements establish distinct intermolecular interactions among F(...

Field studies were established on the alluvial floodplain soils in Louisiana, from 2013 to 2015, to evaluate the effect of silicate slag applications on productivity of wheat (Triticum aestivum), under sufficient and high nitrogen (N) application rates. Treatments were arranged in a randomized complete block design, with four replications consisting of twelve treatments: a factorial combination...

A molecular dynamics study of the aluminosilicate chains structure in Al-rich calcium silicate hydrated (C-S-H) gels A molecular dynamics study of the aluminosilicate chains structure in Al-rich calcium silicate hydrated (C-S-H) gels. Calcium silicate hydrated (C-S-H) gel is the principal binding phase of the cement paste and responsible for its strength. It is basically composed of silicate ch...

Tricalcium silicate cements have been successfully employed in the biomedical field as bioactive bone and dentin substitutes, with widely acclaimed osteoactive properties. This research analyzed the effects of different tricalcium silicate cement formulations on the temporal osteoactivity profile of human bone marrow-derived mesenchymal stem cells (hMW-MSCs). These cells were exposed to four co...