Optimization of Cd (II), Zn (II) and Cu (II) biosorption from contaminated water were performed as function of parameters (pH, contact time, initial metal ions concentration and yeast dose). The experimental results showed that the highest equilibrium adsorption capacity at the optimum pH were 8.5 for Cd (II) and 6 for Zn (II) and 6 for Cu (II). Optimum pH values were carried out to evaluate ot...

Optimization of Cd (II), Zn (II) and Cu (II) biosorption from contaminated water were performed as function of parameters (pH, contact time, initial metal ions concentration and yeast dose). The experimental results showed that the highest equilibrium adsorption capacity at the optimum pH were 8.5 for Cd (II) and 6 for Zn (II) and 6 for Cu (II). Optimum pH values were carried out to evaluate ot...

In the centrosymmetric title compound, [Zn(4)(C(9)H(6)NO)(6)(C(2)H(3)O(2))(2)]·2H(2)O, the Zn(II) atom that is bonded to one O atom of the acetate group is chelated by a quinolin-8-olate anion. This Zn atom is also bonded to the oxide O atoms of two other quinolin-8-olate anions, which themselves engage in chelation to the other Zn(II) atoms. The Zn(II) atom is five-coordinate in a square-pyram...

An intensive study has been made to see the performance of the different liner materials with bentonite on the removal efficiency of Cu(II) and Zn(II) from industrial leachate. An artificial neural network (ANN) was used to display the significant levels of the analyzed liner materials on the removal efficiency. The statistical analysis proves that the effect of natural zeolite was significant ...

Previous studies demonstrated the environmental and economic benefits of treating lead(II)-contaminated water streams with ferrihydrite in multiple equilibrium sorption stages. In this work, multistage ferrihydrite sorption systems were evaluated for their effectiveness in reducing single-solute zinc(II) (Zn(II)) concentrations in contaminated water streams to very low levels. As for lead(II) (...

This study examines metal binding to metallo-β-lactamase VIM-2, demonstrating the first successful preparation of a Co(II)-substituted VIM-2 analogue. Spectroscopic studies of the half- and fully metal loaded enzymes show that both Zn(II) and Co(II) bind cooperatively, where the major species present, regardless of stoichiometry, are apo- and di-Zn (or di-Co) enzymes. We determined the di-Zn VI...

The asymmetric unit of the title compound, tetra-aqua-tetrakis-{μ(3)-6,6'-di-oxido-2,2'-[1,2-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato}octa-zinc(II) dimethyl sulfoxide tetra-solvate dihydrate, [Zn(8)(C(20)H(12)N(2)O(4))(4)(H(2)O)(4)]·4C(2)H(6)OS·2H(2)O, contains one quarter of a Zn(II) octa-nuclear complex with symmetry, one dimethyl sulfoxide mol-ecule and one half of a water mol-ecule w...

The aggregation and supramolecular chirality of the interfacial assemblies of an achiral phthalcyanine derivative, zinc 2,3,9,10,16,17,23,24-octakis(octyloxy)-29 H,31 H-phthaloxyanine (ZnPc), were investigated, and a surface pressure dependent behavior was observed. It was found that ZnPc could be spread as a Langmuir film on water surface and transferred onto solid substrates by the horizontal...

a novel and selective method for the fast determination of trace amounts of zn(ii)ions in water samples has been developed.  the first additional carbonyl and carboxyl functionalized-nano graphene (spfnano graphene). the presence of additional carbonyl and carboxyl groups located at the edge of the sheets makes go sheets strongly hydrophilic, allowing them to readily swell and disperse in water...

We report here two series of coordination polymer chains: the first being [M(II)(ox)(bnz)(2)](n) (M = Mn 1, Fe 2, Co 3, Ni 4, Cu 5 and Zn 6; ox = oxalate C(2)O(4)(2-); bnz = benzimidazole) and the second [M(II)(ox)(btz)(2)](n) (M = Mn 7, Fe 8, Co 9, Ni 10, Cu 11 and Zn 12; btz = benzotriazole). The first series displays an unusual homometallic [-M(i)-M(ii)-M(ii)-](n) chain topology and the seco...