A general, atom-economical method for the synthesis of phosphaalkenes is reported via the net coupling of primary alkyl or aryl phosphines with aryl or alkyl isocyanides at zirconium. The phosphorus-containing ligand can be liberated as the phosphaformamide from zirconium by reaction with an organic electrophile.

A 16-year-old woman with congenitally missing permanent mandibular second premolars and central incisors presented for treatment. The prosthodontic treatment consisted of placing 2 internal tri-lobed narrow platform implants in the mandibular second premolar spaces, along with zirconium abutments and all-ceramic crowns. A 4-unit zirconium fixed partial denture was fabricated to restore the miss...

ABSTRACT The phosphonate-substituted zirconium oxo clusters Zr6O2(OBu)12(O3PPh)4 and Zr7O2(OiPr)12(O3PCH2CH2CH2Br)6, with octahedrally coordinated Zr atoms, were synthesized by reaction of zirconium alkoxides with phosphonic acid bis(trimethylsilyl) esters. The basic structural motif are Zr3O(µ2-OR)3(OR)3 units which are connected in different ways. GRAPHICAL ABSTRACT

The exchange of the monocarboxylate ligand of the zirconium methacrylate oxocluster Zr(6)O(4)(OH)(4)(OMc)(12) (OMc = CH(2)=CH(CH(3))COO) with dicarboxylic acids (trans,trans muconic acid and terephthalic acid) leads to porous zirconium dicarboxylates exhibiting the UiO-66 architecture; the mild reaction conditions allow the control of their particle size.

in this study, isophthalic acid-zirconium(iv) nanocomposite has been prepared from zirconyl nitrate pentahydrate and potassium iodide, with isophthalic acid, (c8h6o4=benzene-1,3-dicarboxylic acid) as a ligand, via sonochemical method in ethylene glycol and methanol as solvents. the crystalline tetragonal zro2 has been produced by thermal decomposition of isophthalic acid-zirconium(iv) nanocompo...

Based on a package of modern analysis methods, the influence various acids and energy effects morphology, elemental composition, structural chemical transformations mineral surface, efficiency eudialyte concentrate leaching was studied. The mechanism optimal conditions specific features destruction rock minerals extraction zirconium REE under acids, powerful nanosecond pulses, dielectric barrie...

Dental ceramics represents a major structural material in fixed prosthodontics. Increasing demands for esthetics led to development of new ceramic materials in order to eliminate the use of metal framework and for all ceramic restorations with mechanical properties to withstand high occlusal forces. Out of all the present ceramic materials, zirconium-ceramic has the best mechanical properties, ...

A series of parasubstituted tetraphenylporphyrin zirconium(IV) salicylate complexes (SA/5-SSAZr(IV)RTPP, R = p-H, p-CH3, p-NO2, p-Cl, SA = salicylate, and 5-SSA = 5-sulfosalicylate) have been synthesized, and the spectral properties of free base porphyrins, their corresponding metallated, and axially ligated zirconium(IV) porphyrin compounds were compared with each other. A detailed analysis of...

J. G. He, Y. Li, X. X. Xue, H. Q. Ru, H. Yang School of Material and Metallurgy, Northeastern University, Shenyang, Liaoning, China. X. W. Huang National Engineering Research Center for Rare Earth Materials, General Research Institute for Nonferrous Metals, and Grirem Advanced Materials Co., Ltd., Beijing, China In this paper the removal of fl uoride from fl uoride-bearing cerium sulfate soluti...

Introduction Zirconium is a fascinating d-orbital transition metal. It has been widely used for nuclear and chemical applications owing to its low neutron absorption cross-section and its exceptional resistance to corrosion. The study of the fundamental thermodynamic properties of zirconium, such as equation of state (EOS) and phase stability, are very important for a better understanding of it...