Reductive desulfurisation of dithiocarbamates is conveniently achieved using H(3)PO(2)-Et(3)N-ACCN in refluxing dioxane. Fused and spirocyclic β-lactams, prepared through 4-exo trig carbamoyl radical cyclisation-dithiocarbamate group transfer reactions, are reduced without fragmentation of the strained 4-membered ring. Diethyl tetraacetyl-d-glucopyranosyl dithiocarbamate is selectively reduced ...

A series of triorganophosphinegold(1) dithiocarbamate (R(3)PAuS(2)CNR'(2)) and xanthate (R(3)PAuS(2)COR') complexes have been prepared and characterised spectroscopically. Based on crystallographic evidence, the molecules feature linear gold(1) geometries defined by sulphur and phosphorus donors. The complexes, along with a series of known anti-cancer agents, have been screened against a panel ...

As discharge restrictions become stricter and sludge dlisposal costs rise, traditional technologies for the removal of metals from plating shop wastewater such as lime and ferric chloride become increasingly less attractive. One technology that is of use of dithiocarbamates to complex a highly insoluble, dense sludge, effluent water and greatly reduced sludge volumes. Despite the benefits avail...

A one-pot preparation of pyridyl isothiocyanates (ITCs) from their corresponding amines has been developed. This method involves aqueous iron(III) chloride-mediated desulfurization of a dithiocarbamate salt that is generated in situ by treatment of an amine with carbon disulfide in the present of DABCO or sodium hydride. The choice of base is of decisive importance for the formation of the dith...

A dithiocarbamate-based methodology is employed to prepare linked heteromultimetallic complexes and then further exploited in the surface functionalisation of gold nanoparticles.

A rare class of mixed-metal [2]catenane has been assembled via magic ring synthesis of dinuclear copper(II) and gold(III) dithiocarbamate macrocycles.

Dithiocarbamate chemistry is used as a crosslinking tool to fabricate FePt colloidal microcapsules which provide a versatile scaffold for "host-guest" recognition at the liquid-liquid interface.

Objective: The coordination and electrochemistry-related effects uses of piperidine dithiocarbamate (pipdtc) piperazine (pzdtc) are the main topics this article. Method: An environment friendly electroless bath was created using a very small amount biodegradable methanesulphonic bronsted acid, Glyoxylic acid as reducing agent, Xylitol non-toxic natural polyhydroxylic complexing agent potassium ...