NaY zeolites with different framework Si/Al ratios were synthesized via hydrothermal technique. Structural characteristics of the synthesized zeolites were determined by using XRD, XRF, SEM, BET analyses. The effects of operating conditions of hydrothermal dealumination, i.e. time, temperature and partial pressure of water vapor on dealumination of the Y zeolites framework and their structure w...

The adsorption isotherms of Fe(CO), on Nay, HY and Linde L zeolites obtained in McBain balances show micropore adsorption, whereas additional capillary condensation is found with zeolite omega and Na-mordenite. The pores and/or cages of the zeolites studied are completely filled with the complex upon saturation, with the exception of Na-mordenite. Their behaviour is explained, respectively, by ...

At atmospheric pressure and at 130-160 degrees C, primary aromatic amines (p-XC6H4NH2, X = H, Cl, NO2) are mono-N-alkylated in a single step, with symmetrical and asymmetrical dialkyl carbonates [ROCOOR', R = Me, R' = MeO(CH2)2O(CH2)2; R = R' = Et; R = R' = benzyl; R = R' = allyl; R = Et, R' = MeO(CH2)2O(CH2)2], in the presence of a commercially available NaY faujasite. No solvents are required...

In the presence of NaY faujasite, dimethyl carbonate (MeOCO(2)Me, DMC) is a highly chemoselective methylating agent of functionalized anilines such as aminophenols (1), aminobenzyl alcohols (2), aminobenzoic acids (3), and aminobenzamides (4). The reaction proceeds with the exclusive formation of N-methylanilines without any concurrent O-methylation or N-/O-methoxy carbonylation side processes....