Solid-state electrochemical sensors using yttria-stabilized zirconia (YSZ) and oxide sensing electrode (SE) were fabricated and examined for NOx detection at high temperatures. Among various single-oxide SEs examined, NiQSE for the mixed-potential-type NOx sensor was found to exhibit rather high sensitivity to N@ even in the high temperature range of 800900°C. This sensor showed quicker respons...

Composite electrodes of yttria-stabilized zirconia (YSZ) with La0.8Sr0.2MnO3 (LSM), La0.8Sr0.2FeO3 (LSF), and La0.8Sr0.2CoO3 (LSCo) were prepared and tested as solid oxide electrolyzer (SOE) anodes and solid oxide fuel cell (SOFC) cathodes at 973 K, using cells with a YSZ electrolyte and a Co-ceria-YSZ counter electrode. The LSM-YSZ electrode was activated by cathodic polarization but the enhan...

Porous composites of Sr0.88Y0.08TiO3-δ (YST) and yttria-stabilized zirconia (YSZ) were formed by tapecasting methods and examined as potential anodes for SOFC. Even after calcination to 1773 K, the YSZ and YST crystallites remain as separate phases, as demonstrated by XRD and SEM with EDX analysis. Furthermore, it was possible to fabricate anode-supported electrolytes by calcination of a bilaye...

The properties of solid oxide fuel cell (SOFC) anode functional layers prepared by impregnation of 1 wt % Pd and 10 wt % ceria into porous scaffolds of either Y0.04Ce0.48Zr0.48O2 (CZY) or composites of La0.3Sr0.7TiO3 (LST) and yttria-stabilized zirconia (YSZ) were examined to determine whether these scaffold materials would have sufficient electronic and ionic conductivity. Laminated tapes were...

An analytical equation is derived for total triple phase boundary length per unit volume (LTPB) in an isotropic uniform random microstructure of LSM/YSZ composite cathode. The equation is applicable to YSZ and LSM particles of any convex shapes and size distributions. The equation explicitly relates LTPB to the shapes, mean sizes, coefficient of variation (a measure of the spread in a size dist...

Ceramic membrane composites consisting of a coarse porous a-alumina or two-layer porous alumina membrane support and an oxygen semipermeable gas tight thin (0.2-5 pm) yttria stabilized zirconia (YSZ) film are prepared by the electrochemical vapor deposition (EVD) method. The minimum gastight thickness of the YSZ films depends strongly on the average pore size of the support on which the films a...

Layered, binary thin-film oxides of NiO, MgO and CaO have been prepared and characterized using low energy electron diffraction, Auger electron spectroscopy, energy loss spectroscopy, ion scattering spectroscopy, and temperature programmed desorption using probe molecules. Epitaxial growth was observed for the NiO–MgO and CaO–NiO systems; however, superior wetting was found for NiO–MgO relative...