Mo carbide nanoparticles supported on ZSM-5 zeolites are promising catalysts for methane dehydroaromatization. For this and other applications, it is important to identify the structure and anchoring sites of Mo carbide nanoparticles. In this work, structures of Mo2Cx (x = 1, 2, 3, 4, and 6) and Mo4Cx (x = 2, 4, 6, and 8) nanoparticles are identified using a genetic algorithm with density funct...

In small-pore zeolite catalysts, where the size of the pores is limited by eight-ring windows, aromatic hydrocarbon pool molecules that are formed inside the zeolite during the Methanol-to-Olefins (MTO) process cannot exit the pores and are retained inside the catalyst. Hydrocarbon species whose size is comparable to the size of the zeolite cage can cause the zeolite lattice to expand during th...

The effectiveness of nanoscale zero-valent iron (nZVI) to remove heavy metals from water is reduced by its low durability, poor mechanical strength, and tendency to form aggregates. A composite of zeolite and nanoscale zero-valent iron (Z–nZVI) overcomes these problems and shows good potential to remove Pb from water. FTIR spectra support nZVI loading onto the zeolite and reduced Fe0 oxidation ...

Nanotechnology can be used to produce slow-release fertilizers. Zeolite and crab shells are materials that as fertilizer encapsulation. This study aimed compare the effects of nano zeolite for encapsulation nitrogen- potassium fertilizers tested on Entisols Inceptisols soil growth yield shallots. The research method a completely randomized design with three factors. factors were type (Entisol I...

The synthesis of calcium silicate supported zeolite membrane was carried out by second growth method. The chemical nature of the functionalizing agent on the formation of homogenous zeolite membrane was evaluated. One monomer and two cationic polymers were used: 3-aminopropyltriethoxysilane (APS), polyethylenimine (PEI) and polydiallyldimethylammonium chloride (PDDA). The support was subjected ...

Zeolite nanoblock (ZNB), prepared by hydrochloric acid decomposition of Na-A type zeolite, works as a highly efficient hydrogen-permeable membrane. Si and Al K-edge X-ray absorption near edge structure (XANES) spectra were measured for ZNB to clarify the local structures. The Si K-edge XANES spectrum is similar to that of the Na-A type zeolite, but the Al K-edge XANES spectrum is interpreted as...

Adoption of new management techniques that improve soil water storage and soil N plant availability yet limit N leaching may help improve environmental quality. A benchtop study was conducted to determine the influence of a single urea fertilizer rate (224 kg N ha) applied with band or fully mixed zeolite (clinoptilolite) application rates (up to 90 Mg ha) on NH4-N and NO3-N concentrations in a...

In the present work, the nano-NaX zeolite and micro-NaX zeolite were synthesized via hydrothermal method. Then, the adsorption capacities and isotherms of pure gases CO2 and CH4 on the synthesized zeolite nanoparticles were determined at three temperatures of 288, 298 and 308 K and various pressures from 1 up to 20 bar. Adsorption capacities of CO2 on the nano-sized zeolites NaX were showed to ...

Fly Ash (FA) from a power station in South Africa was investigated to neutralise and remove contaminants from Acid Mine Drainage (AMD). After this primary treatment the insoluble FA residue namely solid residue (SR) was investigated as a suitable mine backfill material by means of strength testing. Moreover, SR was used to synthesise zeolite-P using a two-step synthesis procedure. Furthermore, ...

A facile and rapid photochemical method for preparing supported silver nanoparticles (Ag-NPs) in a suspension of faujasite type (FAU) zeolite nanocrystals is described. Silver cations are introduced by ion exchange into the zeolite and subsequently irradiated with a Xe-Hg lamp (200 W) in the presence of a photoactive reducing agent (2-hydroxy-2-methylpropiophenone). UV-vis characterization indi...