The iron nanoparticle technology has received considerable attention for its potential applications in groundwater treatment and site remediation. Recent studies have demonstrated the efficacy of zero-valent iron nanoparticles for the transformation of halogenated organic contaminants and heavy metals. In this work, we present a systematic characterization of the iron nanoparticles prepared wit...

Thus far, zero-valent iron has been studied mostly for the degradation of structurally simple oneand two-carbon halogenated organic contaminants such as chlorinated methanes, ethanes, and ethenes. In this research, laboratory synthesized particles of nanoscale iron were explored to degrade lindane, also known as -hexachlorocyclohexane, a formerly widely utilized pesticide and well-documented pe...

High-valent iron(IV)-oxo species have been implicated as the key reactive intermediates in the catalytic cycles of dioxygen activation by heme and non-heme iron enzymes. Our understanding of the enzymatic reactions has improved greatly via investigation of spectroscopic and chemical properties of heme and non-heme iron(IV)-oxo complexes. In this Account, reactivities of synthetic iron(IV)-oxo p...

This work reports on iron-catalysed hydroxylation of benzene and toluene using aqueous H2O2. While benzene is hydroxylated with a high selectivity to phenol, toluene is hydroxylated to cresols with a high selectivity for the ortho and para-position. An inverse KIE indicates the presence of a high valent Fe=O species during catalysis.

Sulfur and iron concentrations in wood from three 17(th) century shipwrecks in the Baltic Sea, the Ghost wreck, the Crown and the Sword, were obtained by X-ray fluorescence (XRF) scanning. In near anaerobic environments symbiotic microorganisms degrade waterlogged wood, reduce sulfate and promote accumulation of low-valent sulfur compounds, as previously found for the famous wrecks of the Vasa ...

The Lewis acidity of boron in diboradiferrocene 1 is strongly enhanced through oxidation of the iron atoms as evident from examination of X-ray structural parameters of the mixed-valent cation 1(+)PF(6) and further confirmed from the strong complexation of MeCN to the dication in 2(2+)(I(3))(2).

A low-valent trinuclear iron complex with an unusual linear Fe(I)-Fe(II)-Fe(I) unit is presented. It is accessed in a rational approach using a salt metathesis reaction between a new anionic Fe(I) containing heterocycle and FeCl2. Its electronic structure was studied by single crystal XRD analysis, EPR and Mössbauer spectroscopy, and magnetic susceptibility measurements.

globally, increasing nitrate concentrations have become a significant environmental problem and a potential risk to public health. the world health organization (who) has set a limit of (10 (mg.l -1 )) no 3 - for human consumption and (100 mg.l -1 )) no 3 - for animals. water above these limits requires denitrification. nitrates causes cancer, blue-bay syndrome, hypertension and thyroid hypertr...

Metal systems have been extensively used for the abiotic remediation of recalcitrant pollutants. Zero-valent metals such as iron (Fe 0 ), zinc (Zn 0 ), magnesium (Mg 0 ) have been used for the reductive dechlorination of organic compounds Nanoscale zero-valent iron particles have been reported to be very effective for the transformation and detoxification of a wide variety of contaminants, such...