Strain-promoted inverse electron-demand Diels-Alder cycloaddition (SPIEDAC) reactions between 1,2,4,5-tetrazines and strained dienophiles, such as bicyclononynes, are among the fastest bioorthogonal reactions. However, the synthesis of 1,2,4,5-tetrazines is complex and can involve volatile reagents. 1,2,4-Triazines also undergo cycloaddition reactions with acyclic and unstrained dienophiles at ...

S-triazines are photosynthetic inhibitors. They have been substituted with co-aminoundecanoic acid. The coupling products have been transformed into triazine aldehydes. These com­ pounds displace radioactive terbutryn and have inhibitory effects on photosynthesis in plants and bacteria. Triazine aldehydes were shown to be effective substrates for bacterial luciferase. A competitive assay betwee...

The 1,3,5-triazine electron acceptor has become one of the most popular building blocks for design thermally activated delayed fluorescence (TADF) materials. Many TADF strategies are first applied in compounds that contain triazines, and there numerous examples organic light-emitting diodes (OLEDs) with triazine-containing emitters show high efficiencies long operating lifetimes. A comprehensiv...

A series of novel fused heterocyclic compounds bearing benzo[4,5]imidazo[1,2-d][1,2,4]triazine 4a-4w were designed and conveniently synthesized via the intermediates 2-(halogenated alkyl)-1H-benzo[d]imidazoles 2a, 2b, and 2-((1-(substituted phenyl)hydrazinyl)alkyl)-1H-benzo[d]imidazoles 3a-3g. The structures of all target compounds were characterized by FT-IR, ¹H NMR, 13C NMR, and EI-MS, of whi...

Reaction of a nucleobase with nitrosonium ion leads to its diazotization. Due to the instability,the nucleobase-diazonium assumingly falls in dediazotization and successive ring openingreactions. The resulting intermediate of the ring opening reaction is able to covalently cross-linkthe opposite strands of DNA. To examine this assumption for cytosine, some 4-amino-5-cyanopyrimidines were synthe...

V ictor B. Curwiel, G ert Schansker, O scar J . de Vos, and Jack J. S. van Rensen Department of Plant Physiology, Agricultural University Wageningen, Arboretumlaan 4, 6703 BD Wageningen, The Netherlands Z. Naturforsch. 4 8 c , 2 7 8 -2 8 2 (1993); received November 26, 1992 Chloroplasts, Triazine-Resistance, Photosystem II, Photoinhibition, Fluorescence Triazine-resistant and susceptible Chenop...

This work includes synthesis a series of some new derivatives triazine from reaction between the sulfur amino acid (L-cysteine) and different aldehydes in dry ethanol to obtain thiazolidine ring as diastereo isomers (Cis Trans)- 2- alkylthiazolidine-4- carboxylic acids (1).
 The (1) suffered esterfication presence drops concentrated sulfuric catalyst give esters :
 ethyl alkylthiazoli...