0022-1694/$ see front matter 2012 Elsevier B.V. A http://dx.doi.org/10.1016/j.jhydrol.2012.09.048 ⇑ Corresponding author. Tel.: +86 2768775432; fax E-mail address: [email protected] (J. Yang). It is a long-lasting challenge in subsurface hydrologic modeling to develop numerically efficient algorithm for coupling unsaturated and saturated flow, especially in regional-scale modeling. In this stud...

One of the most successful relationships for effective stresses on unsaturated soils was proposed by Bishop in the middle of the last century. However, only recently Bishop ́s effective stress equation has been implemented in various constitutive models for unsaturated soils. These models have the advantage of naturally include the coupling between the hydraulic and the mechanical behavior exper...

This paper at first reports an experimental work to test the thermal conductivity of formulated sandy soil specimens of different porosities and water contents. Both needle probe and hot-plate methods were conducted and compared. It has been confirmed that the needle probe method has a better accuracy for the measurement of unsaturated soil thermal conductivity, and that the pore size distribut...

Hematin catalysis of unsaturated lipide oxidation is probably a primary reaction in many types of pathological unsaturated fat oxidation in viva (l-3) and in the spoilage of frozen meat products by oxidative fat rancidity (4). Some of the properties of hematin catalysis have been described (4-8), but knowledge of the reaction mechanism and the reaction products is relatively meager. The catalyt...

An overview of the synthesis and applications of chiral 2,3-epoxy alcohols containing unsaturated chains is presented. One of the fundamental synthetic routes to these compounds is Sharpless asymmetric epoxidation, which is reliable, highly chemoselective and enables easy prediction of the product enantioselectivity. Thus, unsaturated epoxy alcohols are readily obtained by selective oxidation o...

A simple method for the installation of groundwater lysimeters in peat soils was developed which reduces both time and financial effort significantly. The method was applied on several sites in the Rhinluch, a fen peat land 60 km northwest of Berlin, Germany. Over a two-year period, upward capillary flow and evapotranspiration rates under grassland with different groundwater levels were measure...

An analytical solution of macrodispersivity was derived for the adsorbing solute transport in physically and chemically heterogeneous unsaturated soils under the condition of gravity-dominated flow. The unsaturated hydraulic conductivity and water content were treated as spatial random functions. The chemical adsorption was described by a linear equilibrium isotherm, and the adsorption coeffici...

Saturated fatty acids (FA) exert adverse health effects and are more likely to cause insulin resistance and type 2 diabetes than unsaturated FA, some of which exert protective and beneficial effects. Saturated FA, but not unsaturated FA, activate Jun N-terminal kinase (JNK), which has been linked to obesity and insulin resistance in mice and humans. However, it is unknown how saturated and unsa...

Naturally occurring polyhydroxylated amines such as (+)-1-deoxynojirimycin, polyoxamic acid, anisomycin, (-)swainsonine, and alexine stereoisomers, which have interesting biological activities including glucosidase- and mannosidase-inhibitory activity, immunoregulatory activity, and antibacterial effects, were synthesized stereoselectively starting from (S)-pyroglutamic acid derivatives. α,β-Un...

Among the different types of diazocarbonyl substrates found in the literature to date, α,β-unsaturated diazoketones have proven to be very promising as multifunctional intermediates. Possessing a diazo group, a ketone function and a double bond all together in a single molecule, these compounds constitute versatile building blocks for synthesis. For example, double bond functionalization, follo...