Thermodynamics of 23 oligonucleotides with internal single C.T mismatches were obtained by measuring UV absorbance as a function of temperature. Results from these 23 duplexes were combined with three measurements from the literature to derive nearest-neighbor thermodynamic parameters for seven linearly independent trimer sequences with internal C.T mismatches. The data show that the nearest-ne...

In this study, we investigated redox thermodynamics of myoglobin as well as the ionic (phosphate ions) and ligation (imidazole) effects via a dynamic electrochemical approach. We employed a previously established system that features nonmediated, direct electrochemistry of myoglobin and myoglobin in an immobilized state (i.e., diffusionless electrochemistry). Thermodynamics parameters were obta...

This chapter presents an overview of industrial crystallization both from a fundamental, scientific perspective and with an eye on the application of crystallization as a separation process in industrial processes. Crystallization as a separation process yields a solid product from a solution or a melt. The process itself, the product characteristics and the temporal behavior are determined by ...

In the present paper, a Quality Systems Theory is presented. Certifiable Quality Systems are treated and interpreted in accordance with a Thermodynamics-based approach. Analysis is also conducted on the relationship between Quality Management Systems (QMSs) and systems theories. A measure of entropy is proposed for QMSs, including a virtual document entropy and an entropy linked to processes an...

The coexistence of several schools in non-equilibrium thermodynamics is a reality.At the beginning of the 21st century, the thermodynamics of systems far from. However, it turns out that many nonequilibrium phenomena can be described.An alternate evolutionary hypothesis is discussed: non-equilibrium. Literature on non-equilibrium thermodynamics and its relationship to evolutionary.The online ve...

We consider the quasilocal thermodynamics of rotating black holes in asymptotically flat and asymptotically anti de Sitter spacetimes. Using the minimal number of intrinsic boundary counterterms inspired by the AdS/CFT correspondence, we find that we are able to carry out an analysis of the thermodynamics of these black holes for virtually all possible values of the rotation parameter and cosmo...

The paper studies the adsorption of gallic acid from kinetic and thermodynamic perspectives, using several synthesized polymers with amine functional groups. These compounds, defined as P1, P115, P-Ba 2 and PHH, and obtained by appropriate chemical transformation reactions on crosslinked pyridine and acrylic copolymers, were characterized by weight and volume exchange capacities, their values b...

The constraint-based approach to analysis of biochemical systems has emerged as a useful tool for rational metabolic engineering. Flux balance analysis (FBA) is based on the constraint of mass conservation; energy balance analysis (EBA) is based on non-equilibrium thermodynamics. The power of these approaches lies in the fact that the constraints are based on physical laws, and do not make use ...

The kinetic theory is formulated with respect to anholonomic frames of reference on curved spacetimes. By using the concept of nonlinear connection we develop an approach to modelling locally anisotropic kinetic processes and, in corresponding limits, the relativistic non–equilibrium thermodynamics with local anisotropy. This lead to a unified formulation of the kinetic equations on (pseudo) Ri...

DNA hybridization thermodynamics is critical for accurate design of oligonucleotides for biotechnology and nanotechnology applications, but parameters currently in use are inaccurately extrapolated based on limited quantitative understanding of thermal behaviours. Here, we present a method to measure the ΔG° of DNA motifs at temperatures and buffer conditions of interest, with significantly bet...