Seventeen two-photon transitions for neon have been observed in the 580- 635 nm spectral region for use in the spectroscopic study of its higher excited levels, which are not accessible by one-photon absorption. To compare the two and one-photon absorption signals originating from the same lower level, an effort was made to record single-photon optogalvanic spectrum in the available wavele...

With radiation from a synchrotron we measured the spectra of several small molecular species, in the solid phase at 10K, either pure--O2, NO, CO2, N2O, H2O and NH3--or, for NH3, also dispersed in Ar at molar ratio 1/250, from the onset of absorption in the ultraviolet region until the limits of transmission by crystalline LiF or solid Ar. In a quantitative treatment of spectral data, we fitted ...

The detailed electronic structures of fluorescent chromophores are important for their use in imaging of living cells. A series of green fluorescent protein chromophore derivatives is examined by magnetic circular dichroism (MCD) spectroscopy, which allows the resolution of more bands than plain absorption and fluorescence. Observed spectral patterns are rationalized with the aid of time-depend...

The development of clean and renewable energy sources reflects the limited fossil resources and severe environmental problems caused by their combustion. Infinite and inexhaustible solar energy is a key resource to meet a rapidly increasing global demand for energy. Dye-sensitized solar cells (DSSC) are promising devices to generate clean energy as an alternative to the traditional solar cells ...

Transient electronic absorption measurements with 1 ps time resolution follow XeF2 photoproducts in acetonitrile and chlorinated solvents. Ultraviolet light near 266 nm promptly breaks one Xe-F bond, and probe light covering 320-700 nm monitors the products. Some of the cleaved F atoms remain in close proximity to an XeF fragment and perturb the electronic states of XeF. The time evolution of a...

While cellulosic and lignocellulosic materials have been studied using conventional Raman spectroscopy, availability of near-infrared (NIR) Fourier transform (FT) Raman instrumentation has made studying these materials much more convenient.1 This is especially true because the problem of laser-induced fluorescence can be avoided or minimized in FT-Raman (NIR Raman) spectroscopy. More recently, ...

The interaction of the monomeric chlorophyll Q-band electronic transition with solvents of differing physical-chemical properties is investigated through two-dimensional electronic spectroscopy (2DES). Chlorophyll constitutes the key chromophore molecule in light harvesting complexes. It is well-known that the surrounding protein in the light harvesting complex fine-tunes chlorophyll electronic...

Infrared spectroscopy is used to investigate the electronic structure and charge carrier relaxation in crystalline films of CrO2 which is the simplest of all half-metallic ferromagnets. Chromium dioxide is a bad metal at room temperature but it has a remarkably low residual resistivity (,5 mV cm) despite the small spectral weight associated with free carrier absorption. The infrared measurement...

Azo dyes are widely used colorants in consumer products such as leather, textiles, agriculture, cosmetics and in laboratories as indicators. This paper describes the synthesis of some novel azo dyes starting from 3-nitro salicylic acid. The synthesized dyes were investigated for their redox potentials, evaluated for their dying ability on cotton fabrics, resistivity against the fungi growth on ...