نتایج جستجو برای: supported platinum

تعداد نتایج: 215015  

2007
Y. Shao-Horn Sheng Æ S. Chen

This paper discusses the mechanisms of surface area loss of supported platinum (Pt) electrocatalysts in lowtemperature fuel cells. It is argued that submonolayer dissolution of Pt nanoparticles governs the surface area loss at high voltages by increasing the loss of Pt from carbon and coarsening of Pt nanoparticles on carbon.

Journal: :journal of physical & theoretical chemistry 2007
m. vadi a. safavi a. jamshidi

the mono-metallic and bi-metallic catalysts have been prepared by impregnating with solutions containing a compound of h2ptcl6,wo3 and 1ml hcl (0.1 mol). it should be noted that the catalysts’ activity and selectivity have been determined under these conditions : 450-5000c ,and 15-25atm by h2. for converting n-heptane , the molar ratio h2/c7h16 is 5 , and lhsv is 1.5ml/h. it has been proved tha...

2014
Kazuhide Kamiya Ryo Kamai Kazuhito Hashimoto Shuji Nakanishi

Covalent triazine frameworks, which are crosslinked porous polymers with two-dimensional molecular structures, are promising materials for heterogeneous catalysts. However, the application of the frameworks as electrocatalysts has not been achieved to date because of their poor electrical conductivity. Here we report that platinum-modified covalent triazine frameworks hybridized with conductive...

A. Jamshidi A. Safavi M. Vadi

The mono-metallic and bi-metallic catalysts have been prepared by impregnating with solutions containing a compound of H2PtCl6,WO3 and 1ml HCl (0.1 mol). It should be noted that the catalysts’ activity and selectivity have been determined under these conditions : 450-5000C ,and 15-25atm by H2. For converting n-heptane , the molar ratio H2/C7H16 is 5 , and LHSV is 1.5ml/h. It has been proved tha...

Journal: :Physical chemistry chemical physics : PCCP 2015
Juan Corchado-García Luis E Betancourt Carlos A Vélez Sanjaya D Senanayake Dario Stacchiola Kotaro Sasaki Maxime J-F Guinel Yunyun Zhou Chin Li Cheung Carlos R Cabrera

In this study we probe the electrocatalytic activity of Pt nanoparticles supported on ceria nanoparticles (NPs) and nanorods (NRs) in the ethanol oxidation reaction (EOR) in alkaline media. The goal of this study was to relate morphology, support structure and composition to the EOR catalytic activity by using in situ X-ray absorption fine structure (XAFS) studies. Cyclic voltammetry experiment...

Journal: :Catalysis Science & Technology 2023

NH 3 is effectively oxidised on Pt via O-activated dissociation when a minimum particle size to contain favourable surface atom configuration reached. Different mechanisms were found govern oxidation nanoparticles and single sites.

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