The emulsion polymerization of styrene was investigated using polystyrene-b-[polystyrene-r-poly(methacrylic acid)] amphiphilic block-random copolymers (BRCs) different compositions as stabilizers. These stabilizers with molar masses <20,000 g/mol, which possess unique dispersion behaviour (i.e., self-assembly low aggregation numbers) when dissolved in aqueous medium at alkaline pH, were prepare...

higher solid contents (20 % and 40 %) nanocomposites of poly (styrene-co-butyl acrylate) including higher content of cloisite 30b (7 wt% and 10 wt %) were prepared via miniemulsion polymerization. stability of the final latexes proved outstanding combination of polymerization procedure and surfactants. morphological studies revealed by tem, sax and xrd showed three structures of core-shell, arm...

Objective: Bulk-fill composites are a group of composite resins designed for easy and fast filling of large cavities. This study aimed to assess the color stability of bulk-fill composites subjected to xenon radiation and evaluate their color change (&DeltaE) following polymerization. Methods: In this in vitro experimental study, 30 specimens (4mm in height and 8mm in diameter) were fabricat...

objective: bulk-fill composites are a group of composite resins designed for easy and fast filling of large cavities. this study aimed to assess the color stability of bulk-fill composites subjected to xenon radiation and evaluate their color change (&deltae;) following polymerization. methods: in this in vitro experimental study, 30 specimens (4mm in height and 8mm in diameter) were fabricated...

The guanidine hybrid ligands, (tetramethylguanidine)methylenepyridine (TMGpy) and (dimethylethyleneguanidine)methylenepyridine (DMEGpy), were proven to be able to stabilize copper complexes active in the solvent-free polymerization of styrene at 110 °C using 1-phenylethylbromide as the initiator. The polymerization proceeded after first-order kinetics, and polystyrenes with polydispersities aro...

Anionic polymerization is an established process for the synthesis of well-defined block copolymers. Due to high reaction rates, a good knowledge and its heat generation great importance safe control. This be achieved by development validation combined kinetic transport model. The model was based on experimentally anionic homo-polymerization styrene that expanded co-polymerization isoprene carr...

Electrospun nanofibers present a new and rapidly growing research area due to their pronounced micro and nano characteristics associated with high surface area to volume ratio. Poly(styrene-co-acrylamide) and polystyrene polymers were synthesized by boiling temperature soap free emulsion polymerization in aqueous medium with potassium peroxosulphate as the initiator. The resulting polymers were...

Composites of a styrene-isoprene copolymer and SWNTs were prepared by emulsion and miniemulsion polymerization in the presence of SWNTs, aswell as bymixing dispersed SWNTs with a styrene-isoprene copolymer latex after polymerization. For the former, the surfactant was displaced from SWNTs to monomer droplets leading to SWNT aggregation. Mixing dispersed SWNTs with latex after reaction was able ...

Photoinitiated polymerization of styrene in oil/water microemulsions has been successfully performed by using dibenzyl ketone (DBK) as initiator. The system remains transparent during the whole polymerization process. The molecular weights of polymers produced are in the order of IO5, and the polydispersity indexes (PDI) are in the range 1.6-2.2. The particle sizes of the latexes produced are i...