Ternary Cu/ZnO/metal oxide catalysts are prepared through the co-precipitation method under strict control of parameters like pH, calcination conditions, and precipitation temperature in a systematic manner. The metal oxides applied in this study consist of Al2O3, ZrO2, La2O3 and Ce2O3. The distinction of this work in comparison with similar research is a comprehensive investigatation of the ca...

1. Introduction Already in 1868 [1], H 2 was produced by the steam reforming (eq.1) of hydrocarbons in the presence of a calcium oxide, and the use of natural calcium-based sorbents as candidates to remove CO 2 in situ from reactors has been receiving increasing attention. Through simultaneous CO 2 absorption (eq.3) the equilibrium of the homogenous water gas shift reaction (eq.2) is shifted to...

This work initially focuses on developing a computational fluid dynamics (CFD) model of an industrialscale steam methane reforming reactor (reforming tube) used to produce hydrogen. Subsequently, we design and evaluate three different feedback control schemes to drive the area-weighted average hydrogen mole fraction measured at the reforming tube outlet ( x̄H outlet 2 ) to a desired set-point va...

This paper describes a strategy for producing hydrogen via steam reforming of ethylene glycol over supported nickel catalysts. Nickel plays a crucial role in conversion of ethylene glycol and production of hydrogen, while oxide supports affect product distribution of carbonaceous species. A plausible reaction pathway is proposed based on our results and the literature.

Dielectric Barrier Discharges (DBD) operated at atmospheric pressure and working at reduced temperatures (T < 115 degrees C) and a copper-manganese oxide catalyst are combined for the direct decomposition and the steam reforming of methanol (SRM) for hydrogen production and for the preferential oxidation of CO (CO-PROX).

A short time (3-10 min) of microwave irradiation on the CuO/ZnO/Al2O3 oxide precursor can result in a unique tailored microstructural modification on the catalyst, leading to a significantly enhanced performance for H2 production from steam reforming of methanol.

Highly-effective sustainable hydrogen production from ethanol and water was achieved in a tubular dense mixed-conducting oxygen permeable membrane reactor, in which water splitting took place at the tube side of the membrane and oxidative steam reforming of ethanol occurred at the shell side simultaneously.

Introduction Early transition metals carbides are catalytically active in a variety of reactions, such as isomerization reactions, hydrogenation reactions, water-gas shift (WGS), hydrocarbon steam reforming, etc. [1]. Our group recently developed a method to load metal catalysts onto high surface area carbide and nitride supports, and demonstrated that Pt supported on Mo carbide (Mo2C) possesse...

A catalyst and sorbent is disclosed which comprises pellets with an absorbent core and a protective shell with a catalyst in the shell. Such material is especially well suited for steam reforming of hydrocarbons to produce hydrogen since a reforming catalyst can be incorporated in the shell and a sorbent for the by-product carbon dioxide can be used for the core. It is also well suited for prod...

This work describes two different configurations of syngas production processes using a combination of steam methane reforming (SMR) and dry reforming of methane (DRM). The ideal SMR+DRM process ensures the maximum product yield, the heat-integrated SMR+DRM process fulfills the maximum heat recovery, and the stand-alone SMR+DRM process effectively suppress net CO2 emissions. Through kinetic mod...