Magnesium aluminate spinel is one of the most investigated inert matrix materials, due to its good physico-chemical stability, resistance against neutron irradiation, and its thermal conductivity comparable with conventional UO2 fuel. At the HFR in Petten various combinations of actinides and spinel have been tested within the EFTTRA programme, with the object to study the transmutation of amer...

The feasibility of incorporating copper-laden sludge into low-cost ceramic products, such as construction ceramics, was investigated by sintering simulated copper-laden sludge with four aluminum-rich ceramic precursors. The results indicated that all of these precursors (γ-Al(2)O(3), corundum, kaolinite, mullite) could crystallochemically stabilize the hazardous copper in the more durable coppe...

[1] Analysis of high resolution Moon Mineralogy Mapper (M) data reveals the presence of a prominent Mg‐spinel‐rich lithology in the central peaks of Theophilus crater on the lunar nearside. Other peak‐associated lithologies are comprised of plagioclase, olivine, and pyroxene‐bearingmaterials. A consistent spatial association of Mg‐spinel with mafic‐free anorthosite is recognized. Documentation ...

The high voltage spinel LiNi0.5Mn1.5O4 is a promising cathode material in next generation of lithium ion batteries. In this study, LiNi0.5Mn1.5O4 with various particle microstructures are prepared by controlling the microstructures of precursors. LiNi0.5Mn1.5O4 spinel samples with solid, hollow and hierarchical microstructures are prepared with solid MnCO3, hollow MnO2 and hierarchical Mn2O3 as...

Ten chromite ores from ophiolite complexes in SE Iran were analyzed mineralogically by XRD, chemically by XRF, and mineral chemistry by EPMA. The identified paragenesis of silicate minerals of chromite ores with the X-ray diffraction is pronounced differently. It consists of secondary phases formed as serpentine, Cr-containing chlorite (kaemmererite), chromic garnet (uarovite) with preserved pa...

The evolution of interface between the epitaxial thin film LiCoO2 (LCO) electrode and liquid electrolyte and inside the LCO film during electrochemical cycling has been analyzed by high resolution scanning transmission electron microscopy. Relaxation of sharp translational domain boundaries with mismatched layers of CoO2 octahedra occurs during cycling and results in formation of continuous CoO...

Extended X-ray absorption fine structure (EXAFS) and X-ray absorption near-edge structure (XANES) techniques at both Fe and Mn K-edges were used to investigate the formation of MnFe(2)O(4) nanoparticles embedded in a silica aerogel matrix as a function of calcination temperature (at 450, 750 and 900 degrees C). Up to 450 degrees C, two separated highly-disordered phases of iron and manganese ar...

Background Strong magneto-structural coupling in spinel structure results in rich behaviors such as the co-operative Jahn–Teller (JT) distortion and the spin liquid state. To study these effects, NixZn1−xCr2O4 system has been investigated here. These compounds are normal cubic spinel with a space group Fd3̄m above 310 K for NiCr2O4 and at above 12 K for ZnCr2O4. In the normal spinel structure, s...

Introduction. Nickel-rich spinel is recognized as a cosmic event marker [1-3,5]. Spinel is found in K/T boundary sections all over the world [1-3,14], in lower-middle Jurassic hardground [13], in late Pliocene sediments [4] and in upper Eocene sediments [12]. Its composition is characterized by a high nickel oxide concentration (NiO>1 wt%) and a high iron oxidation state (Fe/Fetot>70 mole%) inv...

We report on the synthesis of one-dimensional (1D) Li(4)Ti(5)O(12) nanofibers through electrospinning and their outstanding electrochemical performances. Li(4)Ti(5)O(12) with a spinel structure is a promising candidate anode material for lithium rechargeable batteries due to its well-known zero-strain merits. In order to improve the electronic properties of spinel Li(4)Ti(5)O(12), which are int...