Modification of chitosan biopolymer was achieved by grafting (3-phenyl-1H-pyrazole-4-carbaldehyde) by the Schiff base reaction to synthesize a new chitosan derivative (ChD). The formation of the product was confirmed by FTIR, XRD and CNMR analysis. The grafted molecule provided additional nitrogen bearing groups as binding sites. The new derivative was used to investigate the removal of Cr (VI)...

Many metal-organic frameworks are water labile, including the iconic Hong-Kong University of Science and Technology-1 (HKUST-1). Spray-dry encapsulation of HKUST-1 crystals into polystyrene microspheres is reported here to yield composites that are resistant to water but retain most of the excellent gas sorption capacity of HKUST-1. These composites are demonstrated to exhibit superior water ad...

Acacia polycantha frass (APF) generated by boring activity of Ambrosia beetles was investigated using a batch technique for its potential to adsorb Cr(III) ions from aqueous solution. Studies were carried out to determine the effect of pH, adsorbent dose, and KBr concentration on the sorption behavior Cr(III) on the adsorbent. The adsorption process was found to be highly dependent on solution ...

This article presents a work aiming at thermodynamically and kinetically interpreting the specific sorption and recognition by a molecularly imprinted polymer. Using Boc-L-Phe-OH as a template, the imprinted material was prepared. The result indicates that the prepared polymer can well discriminate the imprint species from its analogue (Boc-D-Phe-OH), so as to adsorb more for the former but les...

The sorption calorimetry method developed by Wadsö and co-workers is one of the most successful methods for studying enthalpy vapor solids gels. A unique feature this a simultaneous measurement water isotherm enthalpy. accuracy measurements in calorimetric experiments can be affected diffusion vapour through injection channel tube potentially small leaks cell. At high activities leads to an app...