This paper describes recent developments in solid-oxide fuel cells (SOFC) that use Cu-based cermets as the anode for direct oxidation of hydrocarbon fuels, including liquids such as gasoline, to generate electrical power without the need for first reforming that fuel to H2. Cu-YSZ cermets were found to be stable in hydrocarbon environments, but exhibited low performance for direct oxidation. Re...

Conversion of fossil fuels to electrical power is the most popular method of electrical power generation. Due to the depletion of fossil fuels and the increase in air pollution, the necessity of using high efficiency power generation systems is increasing. High temperature fuel cells, such as solid oxide fuel cells (SOFC) and molten carbonate fuel cells (MCFC), have high efficiency. According t...

an analytical model is proposed and an analysis is conducted for solid oxide fuel cells with goals of higher power densities. the analytical model is designed to help optimize the size, spacing, and geome-trical shapes of current collectors. the model fully considers the ohmic, species concentration, and activa-tion polarizations. from the analysis of several cases, it is recommended that 3d pi...

Fuel electrode supported microtubular solid oxide fuel cells (SOFC) fabricated at ICMA have been characterized in both solid oxide steam electrolyser (SOEC) and fuel cell modes. The cells consists of a fuel electrode supporting tube of Ni/YSZ with 40% porosity, 400 μm thickness, 2.4 mm diameter and 100-150 mm length, a 15 m thick YSZ electrolyte and a 50vol% LSM/YSZ composite air electrode of...

The slow activity of cathode materials is one of the most significant barriers to realizing the operation of solid oxide fuel cells below 500 °C. Here we report a niobium and tantalum co-substituted perovskite SrCo0.8Nb0.1Ta0.1O3-δ as a cathode, which exhibits high electroactivity. This cathode has an area-specific polarization resistance as low as ∼0.16 and ∼0.68 Ω cm2 in a symmetrical cell an...

In recent years, the need for high efficiency and low emission power generation systems has made much attention to the use of fuel cell technology. The solid oxide fuel cells due to their high operating temperature (800 ℃ -1000 ℃) are suitable for power generation systems.Two-component gas flow (H2 and H2O) in the porous media of solid oxide fuel cell’s anode have been modeled via lattice Boltz...

fuel cells belong to an avant-garde technology family for a wide variety of applications including micro-power, transportation power, stationary power for buildings and other distributed generation applications. the first objective of this contribution is to find a suitable reduced model of a solid oxide fuel cell (sofc). the derived reduced model is then used to design a state estimator. in th...

Digital quantification of a two-dimensional structure was applied to a GDC(Gd₂O₃-doped CeO₂)/LSM(La₀.₈₅Sr₀.₁₅MnO₃) composite cathode employed for solid oxide fuel cells. With the aid of high-resolution imaging capability based on secondary and backscattered electron images, two-dimensional electron micrographs were converted to digital binary files using an image processing tool combined with t...