The switching electrochemical property of an SWNT/DNA hybrid can be produced through reversible conformational changes between the closed and open state originating from the pH-responding i-motif DNA which significantly improves its molecular switching and stability by hydrophobic interactions with SWNTs.

Anisotropic optical absorption properties of single-walled carbon nanotubes (SWNTs) are determined from a vertically aligned SWNT film for 0.5-6 eV. Absorption peaks at 4.5 and 5.25 eV are found to exhibit remarkable polarization dependence and have relevance to optical properties of graphite. A method for determining a nematic order parameter for an aligned SWNT film based on the collinear abs...

We measured the UV optical absorption of single-stranded DNA bound to single-walled carbon nanotubes (DNA/SWNT). The nucleotide absorbance from DNA/SWNT provides the first experimental confirmation that DNA binds to nanotubes through pi-stacking. Because the hypochromic absorbance typical of pi-stacked structures are expected to occur primarily for DNA dipole transitions that lie along the axis...

Flexible single-walled carbon nanotubes/polyaniline (SWNT/PANi) composite films with enhanced thermoelectric properties were prepared via a simple method. Furthermore, these paper-like composite films show good flexibility, which makes them possible to be widely applied in various flexible energy converter devices.

Spectroscopy is a powerful technique to characterize single-walled carbon nanotubes (SWNTs). In particular, photoluminescence (PL) and the excitation spectroscopies have made a great advance in understanding the energy states and transition processes of excitons in SWNTs. The PL spectroscopy also has a potential to assign the chiral index (n,m) of a SWNT and to evaluate the abundance of (n,m) i...

A novel mechanism of SWNT nucleation is considered in oppose to an existing model. The latter model based on the formation of a hemispherical carbon bowl nucleus has no correct description within the thermodynamics and kinetics of the nucleation process. The new mechanism can explain the prevalent formation of [10,10] armchair nanotube on the base of the continuum graphene energetics.

Chemical sensors based on individual single-walled carbon nanotubes (SWNTs) are demonstrated. Upon exposure to gaseous molecules such as NO(2) or NH(3), the electrical resistance of a semiconducting SWNT is found to dramatically increase or decrease. This serves as the basis for nanotube molecular sensors. The nanotube sensors exhibit a fast response and a substantially higher sensitivity than ...

The chemical reactivity of carbon nanotubes in H2SO4 is investigated using individual, single-walled carbon nanotubes (SWNTs) incorporated into electronic devices. Exploiting the device conductance as a sensitive indicator of chemical reactions, discrete oxidation and reduction events can be clearly observed. During oxidation, a SWNT opens circuits to a nanometer-scale tunnel junction with resi...

We report a numerical investigation on the catalytic growth mechanism of a single-walled carbon nanotube (SWNT) inside a template SWNT, that is, formation of a double-walled carbon nanotube (DWNT). The molecular dynamics simulations together with complementary ab inito calculations suggest that the DWNT formation from thermally annealed metallocene-encapsulating SWNT goes through formation of m...

The multi-scale finite element method is used to study the vibrational characteristics of polymer matrix reinforced by single-walled silicon carbide nanotubes. For this purpose, the nanoscale finite element method is employed to simulate the nanotubes at the nanoscale. While, the polymer is considered as a continuum at the larger scale. The polymer nanotube interphase is simulated by spring ele...