Graphite intercalation compounds are formed by inserting guest molecules or ions between sp(2)-bonded carbon layers. These compounds are interesting as synthetic metals and as precursors to graphene. For many decades it has been thought that graphite intercalation must involve host-guest charge transfer, resulting in partial oxidation, reduction or covalent modification of the graphene sheets. ...

in present study, thermo-elastic buckling analysis of multi-layer orthotropic annular/circular graphene sheets is investigated based on eringen’s theory. the moderately thick and also thick nano-plates are considered. using the non-local first and third order shear deformation theories, the governing equations are derived. the van der waals interaction between the layers is simulated for multi-...

The design of graphene-based materials for biomedical purposes is of great interest. Graphene oxide (GO) sheets represent the most widespread type of graphene materials in biological investigations. In this work, thin GO sheets were synthesized and further chemically functionalized with DOTA (1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid), a stable radiometal chelating agent, by an e...

We present a general study on a high performance supercapacitor based on intercalated reduced graphene oxide with carbon black nanoparticles. Graphene oxide sheets were synthesized by oxidation and exfoliation of natural graphite and were reduced using hydroiodic acid in the presence of carbon black nanoparticles. Graphene paper was fabricated by one-step procedure via simultaneous reducing and...

8 Abstract Graphene is a material with extraordinary properties. Its mechanical and electrical properties are unparalleled but the difficulties in its production are hindering its breakthrough in on applications. Graphene is a two-dimensional material made entirely of carbon atoms and it is only a single atom thick. In this work, properties of graphene and graphene based materials are described...

The electronic properties of graphene, such as high charge carrier concentrations and mobilities, make it a promising candidate for next-generation nanoelectronic devices. In particular, electrons and holes can undergo ballistic transport on the sub-micrometre scale in graphene and do not suffer from the scale limitations of current MOSFET technologies. However, it is still difficult to produce...

bending analysis of multilayer graphene sheets (mlgss) subjected to non-uniform shear and normal tractions is presented. the constitutive relations are considered to be non-classical based on nonlocal theory of elasticity. based on the differential transformation method, numerical illustrations are carried out for circular and annular geometries. the effects of nano scale parameter, radius of c...

We have studied the effect of the oxidation path and the mechanical energy input on the size of graphene oxide sheets derived from graphite oxide. The cross-planar oxidation of graphite from the (0002) plane results in periodic cracking of the uppermost graphene oxide layer, limiting its lateral dimension to less than 30 μm. We use an energy balance between the elastic strain energy associated ...

A suspended sheet of pure graphene – a plane layer of C atoms bonded together in a honeycomb lattice – is the “most two-dimensional” system imaginable. Such sheets have long been known to exist in disguised forms – in graphite (many graphene sheets stacked on top of one another), C nanotubes (a graphene sheet rolled into a cylinder) and fullerenes (buckyballs), which are small areas of a graphe...

Graphene sheets have the potential for practical applications in electrochemical devices, but their development has been impeded by critical problems with aggregation of graphene sheets. Here, we demonstrated a facile and bottom-up approach for fabrication of DNA sensor device using water-soluble sulfonated reduced graphene oxide (SRGO) sheets via microwave-assisted sulfonation (MAS), showing e...