Scientific and technological innovations are needed to realize effective production of natural gas hydrates. Whereas global estimates of natural gas hydrate reservoirs are vast, accumulations vary greatly in nature and form. Suboceanic deposits vary from disperse concentrations residing at low saturations in the pore space of unconsolidated sediments with sand-sized particles to higher concentr...

Methane hydrate (MH) is a new energy resource in the 21 century. But the dissociation of MH from sediments during the MH exploration or oil/gas exploration under a hydrate layer accompanied by the softening of soils and formation of excess pore gas pressure may lead to ground failures and environmental disasters. In this study, experiments on modeling the weakening and failure of the sediment b...

Natural gas is projected to be the premium fuel of the 21st century because of availability, as well as economical and environmental considerations. Natural gas is coproduced with water from the subsurface forming gas hydrates. Hydrate formation may result in shutdown of onshore and offshore operations. Industry practice has been usage of alcohols--which have undesirable environmental impacts--...

This paper reports the three-phase (gas + liquid + hydrate) equilibrium pressure versus temperature data for a (O3 + O2 + CO2 + H2O) system for developing the hydrate-based technology to preserve ozone, a chemically unstable substance, for various industrial, medical and consumer uses. These data cover the temperature range from 272 K to 277 K, corresponding to pressures from 1.6 MPa to 3.1 MPa...

This paper reports the three-phase (gas + liquid + hydrate) equilibrium pressure versus temperature data for a (O3 + O2 + CO2 + H2O) system for developing the hydrate-based technology to preserve ozone, a chemically unstable substance, for various industrial, medical and consumer uses. These data cover the temperature range from 272 K to 277 K, corresponding to pressures from 1.6 MPa to 3.1 MPa...

We study diffusive transport of aqueous methane in sea sediments, which is important for formation of methane hydrate and gas deposits and has even been claimed to be principal methane transport mechanism for some geological systems. The isothermal diffusion law (Fick's law), D X = − ∇ J , which is employed in the literature for investigations on methane hydrate, is shown to significantly devia...

In this article, the effect of sodium dodecyl sulfate (SDS) as an anionic surfactant on the thermodynamics, formation rate, formation kinetic, critical micellar concentration (CMC) and stability of methane hydrate was studied. A CMC of SDS and water solution for methane hydrate formation conditions in a batch process was measured at 450 ppm, where CMC was determined by hydrate induction time. I...

Concerns about the potential effects of rising carbon dioxide levels in the atmosphere have stimulated interest in a number of carbon dioxide sequestration studies. One suggestion is the sequestration of carbon dioxide as clathrate hydrates by injection of carbon dioxide into methane hydrate. Energy-supply research estimates indicate that natural gas hydrates in arctic and sub-seafloor formatio...

Researchers at DOE’s National Energy Technology Laboratory (NETL) have been investigating the formation of synthetic gas hydrates, with an emphasis on rapid and continuous hydrate formation techniques. The investigations focused on unconventional methods to reduce dissolution, induction, nucleation and crystallization times associated with natural and synthetic hydrates studies conducted in the...