Controlling cell adhesion on a biomaterial surface is associated with the long-term efficacy of an implanted material. Here we connect the material properties of nanocomposite films made from PEO physically cross-linked with layered silicate nanoparticles (Laponite) to cellular adhesion. Fibroblast cells do not adhere to pure PEO, but they attach to silicate containing nanocomposites. Under aqu...

We have used novel microporous biphenylene-pillared layered silicates as receptors in a quartz crystal microbalance (QCM) for sensing toluene vapors. The silicate was successfully coated on a QCM electrode modified with 2-aminoethanethiol. The resultant electrode showed quantitative frequency responses due to enhanced adhesion between the silicate and the electrode. The silicate-coated electrod...

Coeval silicate melt and aqueous synthetic fluid inclusions were INTRODUCTION formed at 800°C and 2000 bars in the quartz-saturated haploIn recent years the study of silicate melt inclusions has granite–H2O–NaCl–KCl system. The equilibrium assemblage congained considerable popularity as a method to charsisted of Ab19·2Or31·1Qtz49·1 melt, quartz, and an aqueous solution acterize the PTX evolutio...

A model that makes use of the cooperative organization of inorganic and organic molecular species into three dimensionally structured arrays is generalized for the synthesis of nanocomposite materials. In this model, the properties and structure of a system are determined by dynamic interplay among ion-pair inorganic and organic species, so that different phases can be readily obtained through ...

First, the authors mentioned that there were no associated risk factors for silicate stone in any form in the studied child.[1] I presume that the following risk factor ought to be seriously considered. In India, ground water is being used as raw water for 85% public water supply.[2] It was found that all parameters of permissible limit of drinking water, including silicate were not set for all...

This work is intended to provide a better understanding about the properties and roles of the reaction rim in an alkali-silica reaction. A simplified calcium-alkali-silicate system was created to simulate the multiple interactions among reactive silica, alkaline solution and portlandite near the aggregate surface during the formation and evolution of the reaction rim in an alkali-silica reactio...

The synthetic leucite silicate framework mineral analogues Rb2 XSi5O12 {X = Ni [dirubidium nickel(II) penta-silicate] and Mn [dirubidium manganese(II) penta-silicate]} have been prepared by high-temperature solid-state synthesis. The results of Rietveld refinements, using X-ray powder diffraction data collected using Cu Kα X-rays, show that the title compounds crystallize in the space group Pbc...

Precipitation of magnesium silicate from sodium silicate and MgCl2 and MgSO4 solutions was investigated at four different reactant feed rates and two temperatures (25 °C and 50 °C). Sodium silicate solutions were produced from rice hull ash silica. The final product was characterized by scanning electron microscopy, X-ray diffraction, thermogravimetric analysis/differential thermal analysis, cr...

*Correspondence: Mathieu Bauchy , 5731B Boelter Hall, Department of Civil and Environmental Engineering, University of California Los Angeles, Los Angeles, CA 90095-1593, USA e-mail: [email protected] Understanding, predicting, and eventually improving the resistance to fracture for silicate materials is of primary importance to design tougher new glasses suitable for advanced applications. Howev...

A comparison of compressional properties of silicate solids, glasses, and liquids reveals the following fundamental differences: (1) Liquids have much smaller bulk moduli than solids and glasses and the bulk moduli of various silicate melts have a narrow range of values; (2) Liquids do not follow the Birch’s law of corresponding state as opposed to solids and glasses; (3) The Grüneisen paramete...