Shape- and size-controlled supported metal and intermetallic nanocrystallites are of increasing interest because of their catalytic and electrocatalytic properties. In particular, intermetallics PtX (X = Bi, Pb, Pd, Ru) are very attractive because of their high activity as fuel-cell anode catalysts for formic acid or methanol oxidation. These are normally synthesized using high-temperature tech...

msu-s mesoporous catalyst with [sio2]/[al2o3] ratio of 55 was synthesized using tetrapropylammonium hydroxide (tpaoh) as a structure directing agent and hexadecyltrimethylammonium bromide (ctab) as a surfactant. the catalytic activity of the calcined sample was evaluated for the dehydration of methanol to dimethyl ether (dme) in a vertical fixed bed microreactor at a weight hurly space velocity...

Mesoporous nanostructures represent a unique class of photocatalysts with many applications, including splitting of water, degradation of organic contaminants, and reduction of carbon dioxide. In this work, we report a general Lewis acid catalytic template route for the high-yield producing single- and multi-component large-scale three-dimensional (3D) mesoporous metal oxide networks. The large...

Macrocycle-to-framework strategy was explored to prepare covalent organic frameworks (COFs) using shape-persistent macrocycles as multitopic building blocks. We demonstrate well-ordered mesoporous 2D COFs (AEM–COF-1 and AEM–COF-2) can be constructed from tritopic arylene-ethynylene macrocycles, which determine the topology and modulate the porosity of the materials. According to PXRD analysis a...

Platinum nanocubes and nanopolyhedra with tunable size from 5 to 9 nm were synthesized by controlling the reducing rate of metal precursor ions in a one-pot polyol synthesis. A two-stage process is proposed for the simultaneous control of size and shape. In the first stage, the oxidation state of the metal ion precursors determined the nucleation rate and consequently the number of nuclei. The ...

Morphology control of carbon-based nanomaterials (nanocarbons) is critical to practical applications because their physical and chemical properties are highly shape-dependent. The discovery of novel shaped nanocarbons stimulates new development in carbon science and technology. Based on direct reaction of CO2 with Mg metal, we achieved controlled synthesis of several different types of nanocarb...

ABSTRACT i i ABSTRACTi i ABSTRACT In the present work, the elaboration, characterisation and applications of different porous materials have been studied. Porous materials are divided into three categories depending on the porous cavity size, namely microporous materials (pore diameter < 2 nm), mesoporous materials (2 nm < pore diameter < 50 nm) and macroporous materials (pore diameter > 50 nm)...

in this research, mesoporous silica was applied as the host of corrosion inhibitor (molybdate). the loaded mesoporous silica was dispersed in an epoxy matrix. the composite was then coated on the mild steel plate. results showed that the corrosion resistance of the scratched epoxy/mesoporous silica loaded by molybdate was better than the one without molybdate or neat epoxy. on the other hand, e...

We have prepared multifunctional magnetic mesoporous Fe-CaSiO3 materials using triblock copolymer (P123) as a structure-directing agent. The effects of Fe substitution on the mesoporous structure, in vitro bioactivity, magnetic heating ability and drug delivery property of mesoporous CaSiO3 materials were investigated. Mesoporous Fe-CaSiO3 materials had similar mesoporous channels (5-6 nm) with...

the performance of msu-s and its forms modified with phosphotungstic acid (hpw) and nickel (ni) for the desulfurization and denitrogenation of model diesel fuel were studied. according to the results of the characteristic tests (n2 adsorption-desorption, xrd, sem, and nh3-tpd), heteropoly acid incorporation causes higher acidity along with a negligible loss of structural aspects, while ni impre...