A Cu(II)-MOF (1') with open metal sites was readily obtained by removing the coordinated water molecule at 120 °C. It can be used as a probe to evidence the sec-alkyl hydroperoxide species generated from room temperature sec-alcohol auto-oxidation in air. The formed alkyl hydroperoxides can be effectively catalyzed by 1' to decompose into molecular oxygen and corresponding sec-alcohols under am...

(13)C NMR, alone or in combination with (1)H NMR, allows the assignment of the absolute configuration of chiral alcohols, amines, carboxylic acids, thiols, cyanohydrins, sec,sec-diols and sec,sec-aminoalcohols, derivatized with appropriate chiral auxiliaries. This extends the assignment possibilities of NMR to fully deuterated and to nonproton containing compounds.

Purpose We aimed to explore the relationship between thyroid peroxidase antibody (TPO-Ab) and suicidal aggressive behaviors in patients with major mental disorders. Methods enrolled 812 inpatients disorders (schizophrenia, bipolar disorder, depressive disorder) this retrospective study. Baseline interviews were conducted by two psychiatrists. Th...

the aim of this research was to examine the effect of a training interventionprogram on fall-related motor performance in the male elderly with no regularphysical activities. for this purpose, 39 out of 130 participants in screen test wereselected and assigned to training group (n=20) and control group (n=19). subjectsaged between 60 and 70 in experimental were 73.68% and in the control group43...

Objective Letrozole (LTZ) drug is an aromatase inhibitor used for the treatment of hormonally positive breast cancer in postmenopausal women. It has poor water solubility, rapid metabolism and a range side effects. In this study, polymer-based nanoparticles (NPs) incorporating have been formulated evaluated, aimed to control release, potentially maximize therapeutic effici...

<sec>P53 is well recognized to be a tumor suppressor protein. In response the external stress or environmental perturbation, p53 can promote transcription of various target genes downstream, thus regulating cell cycle, apoptosis, DNA repair, and angiogenesis. However, activation further activated by another protein, MDM2, which negatively regulates level inverse reduces p53. This phenomen...