Under solvothermal conditions, the Zn(II) complexes formed from salophen-based ligands with N and O donor atoms are reported. These were initially confirmed through elemental analysis supported by mass spectral data. The purity of was using NMR studies. functional group complexation established FT-IR analysis. Additional supportive information about is also reported molar conductance thermal ba...

Ionic liquid-based dispersive liquid–liquid microextraction (IL– –DLLME) coupled with high performance liquid chromatography (HPLC) with UV detection was developed for the simultaneous extraction and determination of nickel, cobalt, copper and zinc ions. In the proposed approach, salophen (N,N'-bis(salicylidene)-1,2-phenylenediamine) was used as a chelating agent, the ionic liquid, 1-hexyl-3-me...

Ionophore-based ion-exchange nanosphere emulsion was prepared and tested for the determination of thiocyanate. The emulsified nanosphere contained the cationic additive tridodecylmethyl ammonium chloride (TDMAC), the plasticizer, and the ionophore Mn(III)-salophen or Mn(III)-salen. This emulsion was used as titrating agent for thiocyanate complexation with ionophores, which could be transduced ...

A series of iron(III) 1-D polymeric materials of the general formula [Fe(III)(Schiff-base)(L)](BPh(4)).n(CH(3)OH) (Schiff base = N,N'-ethylenebis(salicylaldimine) (H(2)salen), N,N'-o-phenylenebis(salicylaldimine) (H(2)salophen) and N,N'-ethylenebis(acety1acetone)-2,2'-imine (H(2) acen); L = bridging di-pyridyl or di-imidazole ligand, n = 0-4) and analogues therein, have been synthesised and str...

Schiff bases and their metal complexes in the mixtures of ionic liquid (IL) + organic solvent have shown great potential in attractive oxidation catalytic processes. The efficiency of such a process is strongly dependent on the various molecular interactions occurring between components. Thermodynamic properties of these systems can provide valuable information about structural interactions. Th...