B. Synthetic procedures S2 B1. Synthesis of known compounds S2 B2. Synthesis of novel compounds S2 Fully deprotected Ni pyridyl porphyrin dimer NiP2 S2 Phenylacetylene Zn porphyrin tetramer PhC2-ZnP4 S3 Phenylacetylene Ni porphyrin tetramer PhC2-NiP4 S4 Phenylacetylene Ni porphyrin hexamer PhC2-NiP6 S5 Fully THS protected Zn porphyrin heptamer THS-ZnP7, octamer THS-ZnP8 and dodecamer THS-ZnP12 ...

From May 1990 to December 1992.34 intestinal transplantations with or without extra-enteric organs were performed at our center. Of these. I adult patient died intraoperatively, 4 children died during initial hospitalization. and I child died 38 days after discharge. The remaining 28 patients. receiving S8 grafts (n:: 10). S8 and liver (S81L. n :: 14). or multivisceral grafts (MY. n :: 4). were...

Hyperphosphorylation of RPA2 at serine 4 and serine 8 (S4, S8) has been used as a marker for activation of the DNA damage response. What types of DNA lesions cause RPA2 hyperphosphorylation, which kinase(s) are responsible for them, and what is the biological outcome of these phosphorylations, however, have not been fully investigated. In this study we demonstrate that RPA2 hyperphosphorylation...

GENERAL METHODS S4 SYNTHESIS OF SUBSTRATES S4-S6 Synthesis of (Z)and (E)-1-cyclohexyl-1,3-butadiene (8) Typical procedure for the synthesis of (Z)and (E)-1,3-dienes (Z)and (E)-1-Benzylbuta-1,3-diene (18) (Z)and (E)-1-(2-Furyl)-1,3-butadiene (21) (Z)and (E)-1-(4-Butyl-1-cyclohexyl)-1,3-butadiene (22) SYNTHESIS OF COBALT COMPLEXES S7 CHEMOSELECTIVE ASYMMETRIC HYDROVINYLATIONS S7 Asymmetric hydrov...

The open reading frame PA1242 in the genome of Pseudomonas aeruginosa PAO1 encodes a putative protease belonging to the peptidase S8 family of subtilases. The respective enzyme termed SprP consists of an N-terminal signal peptide and a so-called S8 domain linked by a domain of unknown function (DUF). Presumably, this DUF domain defines a discrete class of Pseudomonas proteins as homologous doma...

Motivated by a property of linear resistive electrical networks, we introduce the class of Rayleigh matroids. These form a subclass of the balanced matroids defined by Feder and Mihail [10] in 1992. We prove a variety of results relating Rayleigh matroids to other well–known classes – in particular, we show that a binary matroid is Rayleigh if and only if it does not contain S8 as a minor. This...

Obliquely deposited thin films of ternary Ag–Ge–S glasses are characterized in this work. Thin films are fabricated in a vacuum thermal evaporator at different evaporation angles and examined by Raman spectroscopy. The Raman mode frequency of GeS4 corner-sharing (CS) structure of the as-deposited films display a red-shift as a function of Ag content due to reduced global connectivity, and there...

We examine the vibrational stability of three candidate structures for the B24N24 cage and report their infra-red (IR) and Raman spectra. The candidate structures considered are a round cage with octahedral Øsymmetry, a cage with S4 symmetry that satisfies the isolated square rule, and a cage of S8 symmetry, which combines the caps of the (4,4) nanotube, and contains two extra squares and octag...

Content Synthetic scheme of phosphoramidite 9b ------------------------------------------------------------------S3 Figure S1 ------------------------------------------------------------------------------------------------------S4 Figure S2 ------------------------------------------------------------------------------------------------------S4 Figure S3 -----------------------------------------...