The femtosecond real-time dynamics of the isomerization reaction of trans-stilbene under collisionless conditions are studied using (2+1) resonance-enhanced multiphoton ionization (REMPI) and femtosecond depletion spectroscopy (FDS) in a pump-probe scheme. The observed transients reflect the macroscopic sample anisotropy decay (rotational coherence) and intramolecular vibrational energy redistr...

A reduced order representation of a large data set is often realized through a principal component analysis based upon a singular value decomposition (SVD) of the data. The left singular vectors of a truncated SVD provide the reduced basis. In several applications such as facial analysis and protein dynamics, structural symmetry is inherent in the data. Typically, reflective or rotational symme...

A simple and fast numerical method is developed capable of accurately determining the 3D rotational dynamics of a magnetic particle chain in an infinite fluid domain. The focus is to control the alternating breakup and reformation of the bead chain which we believe is essential to achieve effective fluid mixing at small scales. The numerical scheme makes use of magnetic dipole moments and exten...

Dimension reduction in molecular dynamics simulation is often realized through a principal component analysis based upon a singular value decomposition (SVD) of the trajectory. The left singular vectors of a truncated SVD provide the reduced basis. In many biological molecules, such as HIV1 protease, reflective or rotational symmetry should be present in the molecular configuration. Determining...

Transient direct current photoconductivity (TDCP) is an experimental technique capable of providing information about the sign and magnitude of differences in dipole moment, μ, for the ground state versus an excited state of an uncharged molecular chromophore in solution.2 Briefly, the technique utilizes a static, external electric field to achieve partial orientation of dipolar molecules, as s...

We show that the photoexcitation of the baryon antidecuplet, suggested by the soliton classification of low-lying baryons, is strongly suppressed on the proton target. The process occurs mostly on the neutron target. This qualitative prediction can be useful in identifying the non-exotic members of the antidecuplet in the known baryon spectrum. We also analyze the interrelation between photocou...

The association of two species to form a bound complex, e.g., the binding of a ligand to a protein or the adsorption of a peptide on a lipid membrane, involves an entropy loss, reflecting the conversion of free translational and rotational degrees of freedom into bound motions. Previous theoretical estimates of the standard entropy change in bimolecular binding processes, DeltaS(o), have been d...

Using an α decay level scheme, the fine structure in odd nuclei is explained by taking into account the radial and rotational couplings between the unpaired valence nucleon and the core of the decaying system. It is shown that the experimental behavior of the α decay fine structure phenomenon is governed by the dynamical characteristics of the system.

Fermions and bosons are quite different kinds of particles, but it is possible to unify them in a supermultiplet, by introducing a new mathematical scheme called superalgebra. In this article we discuss the development of the concept of symmetry, starting from the rotational symmetry and finally arriving at this fermion-boson (FB) symmetry.