A water-stable solid electrolyte is a key material without which aqueous lithium–air batteries could not be operated. In this study, we have examined the electrical conductivity and mechanical properties of a water-stable lithium-ion-conducting solid electrolyte, Li1+xAlxGeyTi2−x−y(PO4)3 with the NASICON-type structure, as a function of the Al and Ge content. Li1+xAlxGeyTi2−x−y(PO4)3 was synthe...

alkanedisulfamic acid functionalized silica-coated magnetic nanoparticles (adsa-mnps) were used as effective, low-cost and reusable solid heterogeneous nanomagnetic catalysts for conversion of aldehydes and ketones to corresponding gem-dihydroperoxides and 1,2,4,5-tetraoxanes using aqueous hydrogen peroxide (30% w/w in h2o) at room temperature. these compounds are important key intermediates in...

A simple procedure afforded novel spiroacenaphthylene derivatives in high yields at room temperature from acenaphthenequinone, malononitrile, and phenol derivatives using amino-functionalized silica (SBA-Pr-NH2) as a heterogeneous efficient solid base catalyst. Using SBA-Pr-NH2 in the current procedure presents several advantages, such as a simpler procedure, shorter reaction times, facile synt...

Al2(HPO4)3 was easily prepared and used as a solid acid in acetalization of carbonyl compounds at room temperature and under solvent-free conditions. The protection was done in short reaction times and in good to high isolated yields. The cheapness and availability of this reagent with easy procedure and work-up make this method attractive for the organic synthesis. Keywords—Acetalization, acid...

We have designed a new hypercrosslinked supermicroporous polymer (HMP-1) with a BET surface area of 913 m(2) g(-1) by FeCl3 via a catalyzed Friedel-Crafts alkylation reaction between carbazole and α,α'-dibromo-p-xylene. Upon sulfonation HMP-1 yielded a very efficient solid acid catalyst for the production of biodiesels via esterification/transesterification of free fatty acids (FFA)/esters at r...