نتایج جستجو برای: reductive
تعداد نتایج: 10294 فیلتر نتایج به سال:
Matrix models for a changeable world: the importance of transient dynamics in population management Thomas H. G. Ezard*, James M. Bullock, Harmony J. Dalgleish, Alexandre Millon, Fanie Pelletier, Arpat Ozgul and David N. Koons Imperial College London, Silwood Park Campus, Ascot, Berkshire SL5 7PY, UK; Centre for Ecology and Hydrology, Benson Lane, Crowmarsh Gifford, Wallingford, Oxon OX10 8BB, ...
Organohalides are recalcitrant pollutants that have been responsible for substantial contamination of soils and groundwater. Organohalide-respiring bacteria (ORB) provide a potential solution to remediate contaminated sites, through their ability to use organohalides as terminal electron acceptors to yield energy for growth (i.e., organohalide respiration). Ideally, this process results in non-...
We investigate a class of Lie algebras which we call generalized reductive Lie algebras. These are generalizations of semi-simple, reductive, and affine Kac-Moody Lie algebras. A generalized reductive Lie algebra which has an irreducible root system is said to be irreducible and we note that this class of algebras have been under intensive investigation in recent years. They have also been call...
Reductively metabolized glutamine is a major cellular carbon source for fatty acid synthesis during hypoxia or when mitochondrial respiration is impaired. Yet, a mechanistic understanding of what determines reductive metabolism is missing. Here we identify several cellular conditions where the α-ketoglutarate/citrate ratio is changed due to an altered acetyl-CoA to citrate conversion, and demon...
In this paper we describe the sequence of reactions leading from tetrachloro-para-hydroquinone to 1,2,4-trihydroxybenzene by inducible enzymes of Rhodococcus chlorophenolicus. Tetrachlorohydroquinone was first converted to a dichlorotrihydroxybenzene in a reaction involving both hydrolytic and reductive dechlorination; no trichlorinated intermediate was detected. Dichlorotrihydroxybenzene was s...
Suppose that G is a linearly reductive group. Good degree bounds for generators of invariant rings were given in [2]. Here we study the minimal free resolution of the invariant ring. Recently it was shown that if G is a finite linearly reductive group, then the ring of invariants is generated in degree ≤ |G| (see [5, 6, 3]). This extends the classical result of Noether who proved the bound in c...
Reductive stress, characterised by an increased NADH:NAD+ ratio, may be as common and as important a consequence of redox imbalance as oxidative stress. It may also be an important predisposing cause of the generation of reactive oxygen species. Considerable experimental and indirect clinical evidence suggests that protection against reductive stress depends on biomolecules with electrophilic m...
The C(1)-C(13) fragment of the antimitotic marine macrolide leiodermatolide is prepared in seven steps via hydrogenative and transfer-hydrogenative reductive C-C couplings. A hydrogen-mediated reductive coupling of acetylene with a Roche-type aldehyde is used to construct C(7)-C(13). A 2-propanol-mediated reductive coupling of allyl acetate with (E)-2-methylbut-2-enal at a low loading of iridiu...
Dehalococcoides sp. strain BAV1 couples growth with the reductive dechlorination of vinyl chloride (VC) to ethene. Degenerate primers targeting conserved regions in reductive dehalogenase (RDase) genes were designed and used to PCR amplify putative RDase genes from strain BAV1. Seven unique RDase gene fragments were identified. Transcription analysis of VC-grown BAV1 cultures suggested that bvc...
Reductive elimination of carbon-carbon bonds occurs in numerous metal-catalysed reactions. This process is well documented for a variety of transition metal complexes. However, carbon-carbon bond reductive elimination from a limited number of Au(III) complexes has been shown to be a slow and prohibitive process that generally requires elevated temperatures. Herein we show that oxidation of a se...
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