Electrochemical double-layer capacitors exhibit high power and long cycle life but have low specific energy compared with batteries, limiting applications. Redox-enhanced capacitors increase specific energy by using redox-active electrolytes that are oxidized at the positive electrode and reduced at the negative electrode during charging. Here we report characteristics of several redox electrol...

A bromide–modified silver electrode is reported, in the present study, to catalyze the redox reactions of metalloproteins. This study describes that the bromide ions show very good redox behavior with silver electrode. The cathodic and anodic peak potentials were related to the concentration of bromide ions involved in making bromide-modified silver electrode. The electrode reaction in the brom...

The aqueous electrochemistry of a number of anthraquinone derivatives was studied by using cyclic voltammetry at the surface of carbon paste electrode (CPE). From measurements of the half-wave potential as a function of pH, the potential - pH diagrams were constructed for each compound. The values of formal potentials and the pK'a of some different redox and acid-base couples inv...

The surface of a glassy carbon (GC) electrode was modified with reduced graphene oxide (rGO) to evaluate the electrochemical response of the modified GC electrodes to hydrogen peroxide (H₂O₂) and hydrazine. The electrode potential of the GC electrode was repeatedly scanned from -1.5 to 0.6 V in an aqueous dispersion of graphene oxide (GO) to deposit rGO on the surface of the GC electrode. The s...

The basis of potentiometry is the Nernst equation, which relates the concentration of electroactive species at the surface of an electrode (C) to the potential of that electrode (E); that is, for the reaction O + e = R where E is the formal redox potential of the electron transfer reaction. In a potentiometry experiment, the open-circuit potential (i.e., there is no measurable current through t...

We report an air electrode employing polyimide-coated carbon nanotubes (CNTs) combined with a redox mediator for Li-O2 cells with enhanced electrochemical performance. The polyimide coating on the carbon surface suppresses unwanted side reactions, which decreases the amount of accumulated reaction products on the surface of the air electrode during cycling. The redox mediators lower the overpot...

Aldehyde biosensors were constructed by cross-linking formaldehyde dehydrogenase (FDH) or aldehyde dehydrogenase (ADH) and bovine serum albumin on the surface of a redox Os-polymer-coated electrode. The prepared aldehyde biosensors responded rapidly (within 30 s) to aldehydes without the addition of a soluble mediator, because the inner redox Os-polymer film effectively mediated the electron tr...

We present an innovative electrochemical probe for the monitoring of pH, redox potential and conductivity in near-field rocks of deep geological radioactive waste repositories. The probe is composed of a monocrystalline antimony electrode for pH sensing, four AgCl/Ag-based reference or Cl- selective electrodes, one Ag₂S/Ag-based reference or S2- selective electrode, as well as four platinum ele...

glassy carbon (gc) is the most commonly used carbon-based electrode in the analytical laboratory. because of the high background current and low electrode response, modification of this electrode can be done by various materials and techniques. an ionic liquid (il), 1-methyl-3-(3-trimethoxysilyl propyl) imidazoliumbis (trifluoromethylsulfonyl) imide, was covalently cross linked onto the gc surf...