This article describes additional data related to a research article entitled "Kinetics of Quadruplex to Duplex Conversion" (Mendoza et al. 2015 [1]). We followed the opening reaction of a series of intramolecular G-quadruplex structures by the addition of their corresponding complementary strand. Fluorolabeled complementary strands allowed to monitor the reaction in real-time. An adapted kinet...

The kinetic identification of chemical reaction systems often represents a time-consuming and complex task. This contribution presents an approach that uses rate estimation and feedback linearization to implement effective control without the use of a kinetic model. The reaction rates are estimated by numerical differentiation of reaction variants that are computed from measurements. The approa...

The article is focused on the aspects of using micro-catalytic pulse reactors for studying gas-phase reactions. A literature review includes data regarding different types of micro-catalytic pulse reactor applications in heterogeneous catalysis and the techniques used for estimating kinetic parameters are summarized. The experimental part describes the adaptation of a pyrolysis chromatograph to...

this study is focused on the development of a systematic computational approach which implements genetic algorithm (ga) to find the optimal rigorous kinetic models.a general kinetic model for hydrogenolysis of dibenzothiophene (dbt) based on langmuir-hinshelwood type has been obtained from open literature. this model consists of eight continuous parameters(e.g., arrhenus  and van't hoff paramet...

the removal of as(iii) ions from aqueous solutions has been investigated using silica ceramic under different experimental conditions of initial arsenite concentration, adsorbent dose, temperature and ph. better removal was obtained at temperature 25âºc and ph 7.5. the adsorption data have been explained in terms of langmuir and freundlich equations. the sorption kinetics was tested for the pse...

kinetic monte carlo simulation was applied to investigation of kinetics and mechanism of oxalic acid degradation by direct and heterogeneous catalytic ozonation. la-containing perovskites including lafeo3, lanio3, lacoo3 and lamno3 was studied as catalyst for oxalic acid ozonation. the reaction kinetic mechanisms of each abovementioned catalytic systems has been achieved. the rate constants val...

kinetics of the chemical leaching of chalcocite from a low-grade copper ore in a ferric sulfate medium was investigated using the constrained least square optimization technique. the experiments were carried out for different particle sizes in both the reactor and column at constant eh, ph, and temperature. the leaching rate increased with increase in the temperature. about 50% of the cu recove...

This paper deals with the dynamic modeling of a hydrogen production system using gPROMS. The model includes mass balances, liquid-gas equilibrium relations, mass transfer laws and kinetic reaction equations. The initial reaction mixture is a sodium borohydride solution that reacts via a self-hydrolysis mechanism in the presence of water. The behavior of this system was measured in terms of prod...

This study is focused on the development of a systematic computational approach which implements Genetic Algorithm (GA) to find the optimal rigorous kinetic models.A general Kinetic model for hydrogenolysis of dibenzothiophene (DBT) based on Langmuir-Hinshelwood type has been obtained from open literature. This model consists of eight continuous parameters(e.g., Arrhenus  and Van't...