Hydrodeoxygenated pyrolysis oils (HDO) are considered promising renewable liquid energy carriers. To gain insights in the various reaction pathways taking place during the hydrodeoxygenation reaction of pyrolysis oil, two-dimensional gas chromatography with time-of-flight mass spectrometric analyses (2D-GC-TOF-MS) was applied on the feedstock and product oil. Chromatographic parameters like inj...

The presented study aims to improve the quality of bio-oils by catalytic upgrading of pyrolysis bio-oil from microwave pyrolysis of biomass using transition metal modified activated carbon (AC) catalyst. A central composite experimental design (CCD) was used to optimize the reaction conditions for high quality bio-oil production. The effects of reaction temperature and reaction time on product ...

Two-stage gasification allows power production from biomass and waste with high efficiency. The process involves pyrolysis at about 550°C followed by heating of the pyrolysis gas to about 1300°C in order to crack hydrocarbons and obtain syngas, a mixture of H2, CO, H2O and CO2. The second stage produces soot as unwanted by-product. Experimental results are reported on the suppression of soot fo...

The pyrolysis of waste sludges was investigated using thermogravimetry/mass spectrometry (TG/MS) and a fixed-bed reactor. Two types of sludge were used, namely mixed sludge and oil sludge. In TGA/MS measurements, two degradation steps were observed. Degradation of organic structures, in sludge took place in the first step, while inorganic materials in sludge were mainly decomposed in a second s...

Owing to its low cost and large availability, lignocellulosic biomass is being studied worldwide as a feedstock for renewable liquid biofuels. Lignocellulosic biomass is not currently used as a liquid fuel because economical processes for its conversion have not yet been developed. Currently, there are several routes being studied to convert solid biomass into a liquid fuel which involve multip...

This thesis consists of uncertainty and techno-economic studies of two different biofuels production pathways (catalytic pyrolysis and gasification). The objective of this paper is to obtain a side-by-side techno-economic comparison of in situ and ex situ catalytic pyrolysis, and gasification state-of-technology and target scenarios that addresses both sensitivity and uncertainty analysis in th...

Due to serious environmental problem and strict regulations to control pollution, researchers across the globe are putting their effort to find clean, renewable, greener and cost effective method to produce biochemical from biomass. The aim of this article was to highlight the method to extract phenolic compounds from crude pyrolysis oil using switchable hydrophilicity solvents (SHS). The pyrol...

In order to improve pyrolysis chromatographic analysis of materials that release polar functional groups e.g. carboxylic acids, a simple and rapid methylation method based on TDUpyrolysis/GC-MS in the presence of tetramethylammonium hydroxide (TMAH) was developed. Linseed oil was selected as test material because of its high triglyceride content comprising both saturated and unsaturated fatty a...

Bio-oil from fast pyrolysis of biomass is a low-grade liquid fuel, which can be upgraded through the emulsification with diesel oil. In this study, we prepared two rice husk bio-oil samples with different solid char contents and three bio-oil/diesel-oil emulsion samples with the bio-oil content of 10 wt%, 30 wt% and 50 wt%, respectively. The lubrication properties of these oil samples were eval...

Biomass mainly in the form of wood is the oldest form of energy used by humans. Biomass generally means a relatively dry solid of natural matter that has been specifically grown or has originated as waste or residue from handling such materials. The thermochemical conversion of biomass (pyrolysis, gasification, combustion) is one of the most promising non-nuclear forms of future energy. In the ...