We present a mechanism for the stabilization of colloids in liquid mixtures without use of surfactants or polymers. When a suitable salt is added to a solvent mixture, the coupling of the colloid's surface chemistry and the preferential solvation of ions leads to a repulsive force between colloids that can overcome van der Waals attraction. This repulsive force is substantial in a large range o...

Solvent effects on 2,6-dichloro-4-(2,4,6-triphenyl-pyridinium-1-yl)phenolate [ET (33) dye] and 7diethylamino-3,4-benzophenoxazine-2-one (Nile Red) in binary mixtures of organic solvents (acetone, acetonitrile, propylene carbonate, methanol and ethane-1,2-diol) with 1,3-dialkyl imidazoliumbased ionic liquids were studied by UV-visible spectroscopy. Highly nonlinear behaviour of mixtures of alcoh...

We report a combined experimental and computational study of the structure fragmentation dynamics mixed ligand gas-phase ion-molecule complexes. Specifically, we have studied infrared spectroscopy vibrationally induced photofragmentation mass-selected Au(CO)x(N2O)y+ The structures can be understood on basis local CO N2O chromophores in different solvation shells with found preferentially core. ...

A (general) preferential entailment is defined by a “preference relation” among “states”. States can be either interpretations or sets of interpretations, or “copies” of interpretations or of sets of interpretations, although it is known that the second kind and the fourth one produce the same notion. Circumscription is a special case of the simplest kind, where the states are interpretations. ...

The structure of a single alanine-based Ace-AEAAAKEAAAKA-Nme peptide in explicit aqueous electrolyte solutions (NaCl, KCl, NaI, and KF) at large salt concentrations (3-4 M) is investigated using ≃ 1 μs molecular dynamics (MD) computer simulations. The peptide displays 71% α-helical structure without salt and destabilizes with the addition of NaCl in agreement with experiments of a somewhat long...

Mole fraction solubilities of tadalafil (3) in aqueous mixtures Transcutol® and PEG 400 at temperatures from 298.15 to 333.15 K were analysed following Hildebrand solubility parameters. Cosolvency models for representing various also provided correlation/prediction purposes. Apparent thermodynamic quantities dissolution processes calculated based on van’t Hoff Gibbs equations. Non-linear enthal...

A proton NMR method for the determination of the solvation numbers of alkaline earth cations with dimethylsulfoxide (DMSO) in nitromethane as diluent is described. The method is based on the monitoring of the resonance frequency of DMSO protons as a function of DMSO to metal ion mole ratio while keeping the metal ion concentration constant. The average solvation number of cations at any...

The technical problem addressed in this paper is, given two rule systems for consequence relations X and Y, how to construct Y-approximations of a given X-relation. While an upper Yapproximation can be easily constructed if all Yrules are Horn, the construction of lower Yapproximations is less straightforward. We address the problem by defining the notion of coclosure under co-Horn rules, that ...