Uniform CuO hollow microspheres were successfully achieved from a non-uniform metal organic framework by using a template-free method. The process mechanism has been revealed to be spherical aggregation and Ostwald ripening. When tested in CO oxidation and heat treatment, these assembled microspheres exhibited an excellent catalytic performance and show a much better stability than the inherite...

We first demonstrate a simple "one-pot" method to synthesis uniform Fe3O4 hollow microspheres in the presence of PEG in ethylene glycol by using urea to control their morphologies. The interior cavity of the hollow spheres can be tunable by reaction time. The Lamer model was used to explain the formation of magnetite hollow spherical structures based on the experimental observations. The obtain...

In this communication, a novel one-pot synthetic strategy for preparing hollow PNIPAM microspheres via an interfacial polymerization approach at the interface of an inverse W/O emulsion has been proposed and demonstrated. The results show that the prepared PNIPAM microspheres have real empty core and polymer shell structure, with a size range of 1-3 mum. The hollow microspheres experienced a re...

Zinc-nickel citrate microspheres are prepared by a simple aging process of zinc citrate solid microspheres in nickel nitrate solution. As the concentration of nickel nitrate solution increases, the morphology of the produced zinc-nickel citrate evolves from solid, yolk-shell to hollow microspheres. The formation mechanism of different zinc-nickel citrate microspheres is discussed. After anneali...

A porous-wall hollow glass microsphere (PW-HGM) was investigated as an optical resonator for chemical vapor sensing. A single mode optical fiber taper was used to interrogate the microresonator. Adsorption of chemical molecules into the nanosized pores induced a refractive index change of the thin wall and thus a shift in its resonance spectrum. The PW-HGM resonator had shown higher vapor detec...

Dyes wastewater produced during leather processing caused serious environmental pollution. Anionic dyes are always vital crisis in waste treatment. Removal of anionic dyes from tannery wastewater before their discharge into the environment is important for health and environment safety. The use of low-priced and biodegradable adsorbents could be a good method to minimize the environmental impac...

A microreactor of hollow polymeric microspheres with Pd nanoparticles immobilized in its wall is designed for hydrogenation of olefins under organic/aqueous biphasic catalysis. The microreactor has an ability to encapsulate and concentrate olefins within the vacancy of the hollow microspheres in the aqueous phase, and therefore hydrogenation within the microreactors runs efficiently with concen...

SnO2 microspheres with controllable morphology were prepared via a hydrothermal-annealing method. The SnO2 morphology can be tuned by using AlOOH sol and g-Al2O3 as additive. The hollow SnO2 microspheres with incomplete core-shell structure prepared with small amount of g-Al2O3 presented the best cycling performance in Li-ion battery, exhibiting a specific capacity of 374.2 mAh g 1 up to 100 cy...

Porous polydivinyl benzene (PDVB) microspheres of narrow size distribution were formed by a single-step swelling process of template uniform polystyrene microspheres with divinyl benzene (DVB), followed by polymerization of the DVB within the swollen template microspheres. The PDVB porous particles were then formed by dissolution of the template polystyrene polymer. Unique "cauliflower-like" Zn...

The interest in use of Calcium phosphate (CaP) based glasses as resorbable implantable devices has been steadily increasing due to their unique properties, such as their chemical compositions which can resemble the mineral content of natural bone, controllable degradation profiles coupled with controlled ion release rates and their cytocompatibility [1]. This work focussed on developing both bu...