Water-soluble hydrophobically associating polymers are examined with particular emphasis on their rheology for oilfield applications. The incorporation of a small amount (less than 1 mol%) of hydrophobic groups into the polymer backbone of a water-soluble polymer dramatically alters the rheological properties of the resulting material. Associating polymers have potential for use in mobility con...

Five new aromatic poly(amide-imide)s (5a-e) were synthesized by direct polycondensationreaction of N-(4-carboxy phenyl) trimellitimide (3) with five aromatic diamines (4a-e) by usingtriphenyl phosphite in N-methyl-2-pyrrolidone (NMP) and pyridine at solution containingdissolved CaCl2. All of the polymers were obtained in quantitative yields with inherentviscosities between 0.29-0.40 dL/g. The r...

Title of thesis: ANALYSIS OF RHEOLOGICAL PROPERTIES AND MOLECULAR WEIGHT DISTRIBUTIONS IN CONTINUOUS POLYMERIZATION REACTORS Kedar Himanshu Dave, Master of Science, 2004 Thesis directed by: Professor Kyu Yong Choi Department of Chemical Engineering This work explores the possibility of exploiting structure-property relationships to manufacture tailor-made polymers with target end-use properties...

five new aromatic poly(amide-imide)s (5a-e) were synthesized by direct polycondensationreaction of n-(4-carboxy phenyl) trimellitimide (3) with five aromatic diamines (4a-e) by usingtriphenyl phosphite in n-methyl-2-pyrrolidone (nmp) and pyridine at solution containingdissolved cacl2. all of the polymers were obtained in quantitative yields with inherentviscosities between 0.29-0.40 dl/g. the r...

The main objective of this search was to prepare novel soluble polyureas with improved thermal stability. Accordingly, a new types of polyureas was prepared through the polycondensation reaction of a prepared diamine containing ether, keto, and naphthyl groups with 4,4’-diphenylmethan diisocyanate (MDI), toluene-2,4-diisocyanate (TDI), and isophorone diisocyanate (IPDI) in N-methyl-2-pyrrol...

Bitumen as a binder in coating and insulating materials is modified with polymers to improve its performance in service conditions. Almost all polymers are incompatible with bitumen, and at high temperatures due to relatively very low viscosity of the bitumen phase, are separated from it. These lead to a considerable limitation in the use and handling of polymer-modified bitumens. An understand...

We experimentally investigate the drag-reduced channel flow of an inelastic, shear-thinning rigid polymer solution. Particle image velocimetry and shear-viscosity measurements are used to obtain instantaneous distributions shear viscosity within turbulent domain. elucidate that drag reduction for polymers is primarily driven by a thin lubricating layer consists low-viscosity fluid near wall.

Rheological characteristics of Al2O3, CuO and TiO2 nano particles were investigated in oil asthe base fluid at 1 and 2 wt.%. Constitutive relations for non-Newtonian fluid were discussedbased on the power-law model. Measured viscosities of each nanofluid were used to evaluatethe power-law and consistency index. Results indicated that the nanofluid viscosity decreasedby increasing the concentrat...

in this study, effects of multi walled carbon nanotubes and temperature on rheological behavior of engine oil (10w40) have been examined. for this purpose, the experiments were carried out in the temperature range of 5-55°c for several suspensions with solid volume fractions of 0.025%, 0.05%, 0.1%, 0.25%, 0.5% and 0.75%. the viscosity of all samples was measured in the shear rate range of 666s-...

Research has shown that many Bentonite in Nigeria are unsuitable for oil well drilling in their natural states. Their modification and blends with some additives could increase the yield and boost their suitability. Many indigenous polymers have become very popular due to environmental friendliness and their ability to modify rheology of clay suspension. However, the common natural polymers are...