The hybrid hydrogel materials meet important social challenges, including the photocatalytic purification of water and bio-medical applications. Here, we demonstrate two scenarios polyacrylamide-TiO2 (PAAm@TiO2) composite design using calcium alginate (Alg-Ca) or Keplerate-type polyoxometalates (POMs) {Mo132} tuning polymer network structure. Calcium molding allowed us to produce polyacrylamide...