The effect of hydrocarbon chain length on chemical selectivity in micellar electrokinetic chromatography (MEKC) was investigated using polymeric sulfated surfactants: poly-(sodium 7-octenyl sulfate), poly(sodium 8-nonenyl sulfate), poly(sodium 9-decenyl sulfate), and poly(sodium 10-undecenyl sulfate). Linear solvation energy relationships (LSERs) and free energy of transfer studies were conduct...

Due to the importance and various applications of nitriles especially in medicinal productions, a new method for conversion of aldehydes to nitriles has been presented. Several nitrile-containing aromatic compounds were synthesized through the treatment of various aldehydes and hydroxylamine hydrochloride as nucleophile in the presence of ferric hydrogen sulfate as a heterogeneous, efficient, a...

Introduction: The Mars Exploration Rover (MER) missions have stimulated considerable thinking about the surficial geochemical evolution of Mars [1-4]. Among the major MER findings is the presence of the mineral, jarosite (a ferric sulfate salt), which suggests formation from an acid-sulfate brine. The objectives of this work were to (1) add ferric iron chemistry to an existing ferrous iron mode...

OBJECTIVE To estimate efficacy of rapid, large-dose intravenous (IV) administration of ferric carboxymaltose compared with oral iron therapy in anemic postpartum women. METHODS In a randomized, controlled trial, we assigned anemic women (hemoglobin [Hb] less than or equal to 10 g/dL) within 10 days postpartum to receive either IV ferric carboxymaltose (less than or equal to 1,000 mg over 15 m...

The periplasmic protein FepB of Escherichia coli is a component of the ferric enterobactin transport system. We overexpressed and purified the binding protein 23-fold from periplasmic extracts by ammonium sulfate precipitation and chromatographic methods, with a yield of 20%, to a final specific activity of 15,500 pmol of ferric enterobactin bound/mg. Periplasmic fluid from cells overexpressing...

A method for direct, continuous determination of ferric ions produced in autotrophic iron oxidation, which depends upon the measurement of ferric ion absorbance at 304 nm, is described. The use of initial rates is shown to compensate for such changes in extinction during oxidation, which are due to dependence of the extinction coefficient on the ratio of complexing anions to ferric ions. A grap...

To determine cholesterolin biologicalfluids,use of the ferric chloride-sulfuric acid reagent introduced by Zlatkis et al. (1) is relatively simple and reliable (2, 3), and the sensitivityof the reagent for cholesterol is four to five times greater than that of the Liebermann-Burchard reagent (2). However, Parekh and Jung (4) reported that hydrogen chloride is evolved during the ferric chloride-...