Segregation and phase separation of aliovalent dopants on perovskite oxide (ABO3) surfaces are detrimental to the performance of energy conversion systems such as solid oxide fuel/electrolysis cells and catalysts for thermochemical H2O and CO2 splitting. One key reason behind the instability of perovskite oxide surfaces is the electrostatic attraction of the negatively charged A-site dopants (f...

A set of multicomponent perovskite oxide nanoparticles based on La1-xSrxCo1-yFeyO3-δ(LSCF) were prepared by a simple chemical precipitation method for application in low temperature solid oxide fuel cells (LT-SOFC) as cathode materials.  The precursor materials used in this synthesis were lanthanum nitrate hexahydrate [La(NO3)<su...

Nano-structured CuO-Cu2O complex thin film-based perovskite solar cells were fabricated on an indium tin oxide (ITO)-coated glass and studied. Copper (Cu) thin films with a purity of 99.995 % were deposited on an ITO-coated glass by magnetron reactive sputtering. To optimize the properties of the nano-structured CuO-Cu2O complex thin films, the deposited Cu thin films were thermally oxidized at...

Catalysts with the formula of LaCo(1+x)O(3+δ), where 0 ≤ x ≤ 1, were studied for oxidation of CO and C2H6 in a synthetic exhaust gas, comprising 6.0 % CO and 0.2 % C2H6 in Ar. Ethane was selected as a model for hydrocarbons in the exhaust gas. The performance of catalysts is correlated to their properties, particularly their ...

Researchers have demonstrated that BiFeO3 exhibits ferroelectric hysteresis but none have shown a strong ferromagnetic response in either bulk or thin film without significant structural or compositional modification. When remanent magnetisations are observed in BiFeO3 based thin films, iron oxide second phases are often detected. Using aberration-corrected scanning transmission electron micros...

Perovskite materials host an incredible variety of functionalities. Although the lightest element, hydrogen, is rarely encountered in oxide perovskite lattices, it was recently observed as the hydride anion H(-), substituting for the oxide anion in BaTiO3. Here we present a series of 30 new complex hydride perovskite-type materials, based on the non-spherical tetrahydroborate anion BH4(-) and n...

The discovery of two-dimensional electron gases at the heterointerface between two insulating perovskite-type oxides, such as LaAlO(3) and SrTiO(3), provides opportunities for a new generation of all-oxide electronic devices. Key challenges remain for achieving interfacial electron mobilities much beyond the current value of approximately 1,000 cm(2) V(-1) s(-1) (at low temperatures). Here we c...

The defect tolerance of halide perovskite materials has led to efficient optoelectronic devices based on thin-film geometries with unprecedented speed. Moreover, it has motivated research on perovskite nanowires because surface recombination continues to be a major obstacle in realizing efficient nanowire devices. Recently, ordered vertical arrays of perovskite nanowires have been realized, whi...

This work introduces an aprotic sulfonium buffer layer at the nickel oxide–perovskite heterojunction to eliminate multi-step photochemical reactions, which leads inverted perovskite solar cells with long-term operational stability.

Submitted for the MAR07 Meeting of The American Physical Society Doping variation of orbitally-induced anisotropy in electronic structure of the perovskite-type vanadium oxides JUN FUJIOKA, SHIGEKI MIYASAKA, Dept. of Appl. Phys., Univ. of Tokyo, YOSHINORI TOKURA, Dept. of Appl. Phys., Univ. of Tokyo, ERATO-SSS, AIST-CERC — Recently, the perovskite-type vanadium oxide LaVO3 has been attracting m...